Jacobsen Group Paper of the Year Master List


Angew. Chem. Int. Ed.

1. Foldamer‐Mediated Remote Stereocontrol: >1,60 Asymmetric Induction

Byrne, Liam; Solà, Jordi; Boddaert, Thomas; Marcelli, Tommaso; Adams, Ralph W.; Morris, Gareth A.; Clayden, Jonathan. Angew. Chem. Int. Ed. 2014, 53, 151–155. DOI: 10.1002/anie.201308264


2. Enantioselective Formation of All‐Carbon Quaternary Stereocenters from Indoles and Tertiary Alcohols Bearing A Directing Group

Zhao, Wanxiang; Wang, Zhaobin; Chu, Boyang; Sun, Jianwei. Angew. Chem. Int. Ed. 2015, 54, 1910–1913. DOI: 10.1002/anie.201405252


3. A Practical Aryl Unit for Azlactone Dynamic Kinetic Resolution: Orthogonally Protected Products and A Ligation‐Inspired Coupling Process

Tallon, Sean; Manoni, Francesco; Connon, Stephen J.. Angew. Chem. Int. Ed. 2015, 54, 813–817. DOI: 10.1002/anie.201406857


4. Terminal Phosphanido Rhodium Complexes Mediating Catalytic PP and PC Bond Formation

Geer, Ana M.; Serrano, Ángel L.; de Bruin, Bas; Ciriano, Miguel A.; Tejel, Cristina. Angew. Chem. Int. Ed. 2015, 54, 472–475. DOI: 10.1002/anie.201407707


5. Asymmetric Synthesis of 2,3‐Dihydropyrroles by Ring‐Opening/Cyclization of Cyclopropyl Ketones Using Primary Amines

Xia, Yong; Liu, Xiaohua; Zheng, Haifeng; Lin, Lili; Feng, Xiaoming. Angew. Chem. Int. Ed. 2015, 54, 227–230. DOI: 10.1002/anie.201407880


6. Air‐Stable Cationic Gold(I) Catalyst Featuring a Z‐Type Ligand: Promoting Enyne Cyclizations

Inagaki, Fuyuhiko; Matsumoto, Chiaki; Okada, Yasuhiko; Maruyama, Naoya; Mukai, Chisato. Angew. Chem. Int. Ed. 2015, 54, 818–822. DOI: 10.1002/anie.201408037


7. Metal‐Free Carbonylations by Photoredox Catalysis

Majek, Michal; Jacobi von Wangelin, Axel. Angew. Chem. Int. Ed. 2015, 54, 2270–2274. DOI: 10.1002/anie.201408516


8. Silver‐Catalyzed Arylation of (Hetero)arenes by Oxidative Decarboxylation of Aromatic Carboxylic Acids

Kan, Jian; Huang, Shijun; Lin, Jin; Zhang, Min; Su, Weiping. Angew. Chem. Int. Ed. 2015, 54, 2199–2203. DOI: 10.1002/anie.201408630


9. Aerobic Palladium‐Catalyzed Dioxygenation of Alkenes Enabled by Catalytic Nitrite

Wickens, Zachary K.; Guzmán, Pablo E.; Grubbs, Robert H.. Angew. Chem. Int. Ed. 2015, 54, 236–240. DOI: 10.1002/anie.201408650


10. Ligand‐Promoted ortho‐CH Amination with Pd Catalysts

Zhu, Dajian; Yang, Guoqiang; He, Jian; Chu, Ling; Chen, Gang; Gong, Wei; Chen, Ke; Eastgate, Martin D.; Yu, Jin‐Quan. Angew. Chem. Int. Ed. 2015, 54, 2497–2500. DOI: 10.1002/anie.201408651


11. Enantioselective Construction of Vicinal Tetrasubstituted Stereocenters by the Mannich Reaction of Silyl Ketene Imines with Isatin‐Derived Ketimines

Zhao, Jiannan; Fang, Bing; Luo, Weiwei; Hao, Xiaoyu; Liu, Xiaohua; Lin, Lili; Feng, Xiaoming. Angew. Chem. Int. Ed. 2015, 54, 241–244. DOI: 10.1002/anie.201408730


12. Reversing the Stereoselectivity of a Palladium‐Catalyzed O‐Glycosylation through an Inner‐Sphere or Outer‐Sphere Pathway

Xiang, Shaohua; Hoang, Kim Le Mai; He, Jingxi; Tan, Yu Jia; Liu, Xue‐Wei. Angew. Chem. Int. Ed. 2015, 54, 604–607. DOI: 10.1002/anie.201408739


13. Metal‐Free σ‐Bond Metathesis in 1,3,2‐Diazaphospholene‐Catalyzed Hydroboration of Carbonyl Compounds

Chong, Che Chang; Hirao, Hajime; Kinjo, Rei. Angew. Chem. Int. Ed. 2015, 54, 190–194. DOI: 10.1002/anie.201408760


14. Metal‐Free, Room‐Temperature, Radical Alkoxycarbonylation of Aryldiazonium Salts through Visible‐Light Photoredox Catalysis

Guo, Wei; Lu, Liang‐Qiu; Wang, Yue; Wang, Ya‐Ni; Chen, Jia‐Rong; Xiao, Wen‐Jing. Angew. Chem. Int. Ed. 2015, 54, 2265–2269. DOI: 10.1002/anie.201408837


15. Interception of Cobalt‐Based Carbene Radicals with α‐Aminoalkyl Radicals: A Tandem Reaction for the Construction of β‐Ester‐γ‐amino Ketones

Zhang, Jie; Jiang, Jiewen; Xu, Dongmei; Luo, Qiang; Wang, Hongxiang; Chen, Jijun; Li, Huihuang; Wang, Yaxiong; Wan, Xiaobing. Angew. Chem. Int. Ed. 2015, 54, 1231–1235. DOI: 10.1002/anie.201408874


16. CH Functionalization of Phenols Using Combined Ruthenium and Photoredox Catalysis: In Situ Generation of the Oxidant

Fabry, David C.; Ronge, Meria A.; Zoller, Jochen; Rueping, Magnus. Angew. Chem. Int. Ed. 2015, 54, 2801–2805. DOI: 10.1002/anie.201408891


17. Phase‐Transfer‐Catalyzed Asymmetric SNAr Reaction of α‐Amino Acid Derivatives with Arene Chromium Complexes

Shirakawa, Seiji; Yamamoto, Kenichiro; Maruoka, Keiji. Angew. Chem. Int. Ed. 2015, 54, 838–840. DOI: 10.1002/anie.201409065


18. Copper‐Catalyzed Stereoselective Aminoboration of Bicyclic Alkenes

Sakae, Ryosuke; Hirano, Koji; Satoh, Tetsuya; Miura, Masahiro. Angew. Chem. Int. Ed. 2015, 54, 613–617. DOI: 10.1002/anie.201409104


19. Stereospecific and Stereoselective Rhodium(I)‐Catalyzed Intramolecular [2+2+2] Cycloaddition of Allene‐Ene‐Ynes: Construction of Bicyclo[4.1.0]heptenes

Ohta, Yuu; Yasuda, Shigeo; Yokogawa, Yuka; Kurokawa, Kei; Mukai, Chisato. Angew. Chem. Int. Ed. 2015, 54, 1240–1244. DOI: 10.1002/anie.201409155


20. Stereodivergent Synthesis of Arylcyclopropylamines by Sequential CH Borylation and Suzuki–Miyaura Coupling

Miyamura, Shin; Araki, Misaho; Suzuki, Takayoshi; Yamaguchi, Junichiro; Itami, Kenichiro. Angew. Chem. Int. Ed. 2015, 54, 846–851. DOI: 10.1002/anie.201409186


21. Enantiotopos‐Selective CH Oxygenation Catalyzed by a Supramolecular Ruthenium Complex

Frost, James R.; Huber, Stefan M.; Breitenlechner, Stefan; Bannwarth, Christoph; Bach, Thorsten. Angew. Chem. Int. Ed. 2015, 54, 691–695. DOI: 10.1002/anie.201409224


22. B(C6F5)3‐Catalyzed Transfer Hydrogenation of Imines and Related Heteroarenes Using Cyclohexa‐1,4‐dienes as a Dihydrogen Source

Chatterjee, Indranil; Oestreich, Martin. Angew. Chem. Int. Ed. 2015, 54, 1965–1968. DOI: 10.1002/anie.201409246


23. Cobalt‐Catalyzed CH Cyanation of Arenes and Heteroarenes

Li, Jie; Ackermann, Lutz. Angew. Chem. Int. Ed. 2015, 54, 3635–3638. DOI: 10.1002/anie.201409247


24. Synergistic Steric Effects in the Development of a Palladium‐Catalyzed Alkyne Carbohalogenation: Stereodivergent Synthesis of Vinyl Halides

Le, Christine M.; Menzies, Perry J. C.; Petrone, David A.; Lautens, Mark. Angew. Chem. Int. Ed. 2015, 54, 254–257. DOI: 10.1002/anie.201409248


25. Hydrogenations at Room Temperature and Atmospheric Pressure with Mesoionic Carbene‐Stabilized Borenium Catalysts

Eisenberger, Patrick; Bestvater, Brian P.; Keske, Eric C.; Crudden, Cathleen M.. Angew. Chem. Int. Ed. 2015, 54, 2467–2471. DOI: 10.1002/anie.201409250


26. Enantioselective Oxidative Gold Catalysis Enabled by a Designed Chiral P,N‐Bidentate Ligand

Ji, Kegong; Zheng, Zhitong; Wang, Zhixun; Zhang, Liming. Angew. Chem. Int. Ed. 2015, 54, 1245–1249. DOI: 10.1002/anie.201409300


27. Asymmetric Dual‐Reagent Catalysis: Mannich‐type Reactions Catalyzed by Ion Pair

Wang, Hong‐Yu; Zhang, Kai; Zheng, Chang‐Wu; Chai, Zhuo; Cao, Dong‐Dong; Zhang, Jia‐Xing; Zhao, Gang. Angew. Chem. Int. Ed. 2015, 54, 1775–1779. DOI: 10.1002/anie.201409342


28. Transition‐Metal‐Free Formal Decarboxylative Coupling of α‐Oxocarboxylates with α‐Bromoketones under Neutral Conditions: A Simple Access to 1,3‐Diketones

He, Zhen; Qi, Xiaotian; Li, Shiqing; Zhao, Yinsong; Gao, Ge; Lan, Yu; Wu, Yiwei; Lan, Jingbo; You, Jingsong. Angew. Chem. Int. Ed. 2015, 54, 855–859. DOI: 10.1002/anie.201409361


29. The Catalytic Asymmetric Abramov Reaction

Guin, Joyram; Wang, Qinggang; van Gemmeren, Manuel; List, Benjamin. Angew. Chem. Int. Ed. 2015, 54, 355–358. DOI: 10.1002/anie.201409411


30. Palladium versus Platinum: The Metal in the Catalytic Center of a Molecular Photocatalyst Determines the Mechanism of the Hydrogen Production with Visible Light

Pfeffer, Michael G.; Schäfer, Bernhard; Smolentsev, Grigory; Uhlig, Jens; Nazarenko, Elena; Guthmuller, Julien; Kuhnt, Christian; Wächtler, Maria; Dietzek, Benjamin; Sundström, Villy; Rau, Sven. Angew. Chem. Int. Ed. 2015, 54, 5044–5048. DOI: 10.1002/anie.201409438


31. Highly Diastereo‐ and Enantioselective Palladium‐Catalyzed [3+2] Cycloaddition of Vinyl Aziridines and α,β‐Unsaturated Ketones

Xu, Chao‐Fan; Zheng, Bao‐Hui; Suo, Jia‐Jia; Ding, Chang‐Hua; Hou, Xue‐Long. Angew. Chem. Int. Ed. 2015, 54, 1604–1607. DOI: 10.1002/anie.201409467


32. A Highly cis‐Selective and Enantioselective Metal‐Free Hydrogenation of 2,3‐Disubstituted Quinoxalines

Zhang, Zhenhua; Du, Haifeng. Angew. Chem. Int. Ed. 2015, 54, 623–626. DOI: 10.1002/anie.201409471


33. Oxidative Enantioselective α‐Fluorination of Aliphatic Aldehydes Enabled by N‐Heterocyclic Carbene Catalysis

Li, Fangyi; Wu, Zijun; Wang, Jian. Angew. Chem. Int. Ed. 2015, 54, 656–659. DOI: 10.1002/anie.201409473


34. X‐Ray Characterization of an Electron Donor–Acceptor Complex that Drives the Photochemical Alkylation of Indoles

Kandukuri, Sandeep R.; Bahamonde, Ana; Chatterjee, Indranil; Jurberg, Igor D.; Escudero‐Adán, Eduardo C.; Melchiorre, Paolo. Angew. Chem. Int. Ed. 2015, 54, 1485–1489. DOI: 10.1002/anie.201409529


35. Direct Asymmetric Dearomatization of 2‐Naphthols by Scandium‐Catalyzed Electrophilic Amination

Nan, Jiang; Liu, Jingjing; Zheng, Huayu; Zuo, Zhijun; Hou, Lei; Hu, Huaiming; Wang, Yaoyu; Luan, Xinjun. Angew. Chem. Int. Ed. 2015, 54, 2356–2360. DOI: 10.1002/anie.201409565


36. Catalytic Asymmetric Intramolecular Homologation of Ketones with α‐Diazoesters: Synthesis of Cyclic α‐Aryl/Alkyl β‐Ketoesters

Li, Wei; Tan, Fei; Hao, Xiaoyu; Wang, Gang; Tang, Yu; Liu, Xiaohua; Lin, Lili; Feng, Xiaoming. Angew. Chem. Int. Ed. 2015, 54, 1608–1611. DOI: 10.1002/anie.201409572


37. Chloroacetate‐Promoted Selective Oxidation of Heterobenzylic Methylenes under Copper Catalysis

Liu, Jianming; Zhang, Xin; Yi, Hong; Liu, Chao; Liu, Ren; Zhang, Heng; Zhuo, Kelei; Lei, Aiwen. Angew. Chem. Int. Ed. 2015, 54, 1261–1265. DOI: 10.1002/anie.201409580


38. Cooperative Catalysis of Noncompatible Catalysts through Compartmentalization: Wacker Oxidation and Enzymatic Reduction in a One‐Pot Process in Aqueous Media

Sato, Hirofumi; Hummel, Werner; Gröger, Harald. Angew. Chem. Int. Ed. 2015, 54, 4488–4492. DOI: 10.1002/anie.201409590


39. Design and Enantioselective Synthesis of Cashmeran Odorants by Using “Enol Catalysis”

Felker, Irene; Pupo, Gabriele; Kraft, Philip; List, Benjamin. Angew. Chem. Int. Ed. 2015, 54, 1960–1964. DOI: 10.1002/anie.201409591


40. A General Synthesis of Fluoroalkylated Alkenes by Palladium‐Catalyzed Heck‐Type Reaction of Fluoroalkyl Bromides

Feng, Zhang; Min, Qiao‐Qiao; Zhao, Hai‐Yang; Gu, Ji‐Wei; Zhang, Xingang. Angew. Chem. Int. Ed. 2015, 54, 1270–1274. DOI: 10.1002/anie.201409617


41. Ligand‐Controlled Regiodivergent Nickel‐Catalyzed Annulation of Pyridones

Donets, Pavel A.; Cramer, Nicolai. Angew. Chem. Int. Ed. 2015, 54, 633–637. DOI: 10.1002/anie.201409669


42. AgF‐Mediated Fluorinative Cross‐Coupling of Two Olefins: Facile Access to α‐CF3 Alkenes and β‐CF3 Ketones

Gao, Bing; Zhao, Yanchuan; Hu, Jinbo. Angew. Chem. Int. Ed. 2015, 54, 638–642. DOI: 10.1002/anie.201409705


43. Rhodium‐Catalyzed Asymmetric Synthesis of Silicon‐Stereogenic Dibenzosiloles by Enantioselective [2+2+2] Cycloaddition

Shintani, Ryo; Takagi, Chihiro; Ito, Tomoaki; Naito, Masanobu; Nozaki, Kyoko. Angew. Chem. Int. Ed. 2015, 54, 1616–1620. DOI: 10.1002/anie.201409733


44. Highly Enantioselective Intermolecular Cross Rauhut–Currier Reaction Catalyzed by a Multifunctional Lewis Base Catalyst

Dong, Xuelin; Liang, Ling; Li, Erqing; Huang, You. Angew. Chem. Int. Ed. 2015, 54, 1621–1624. DOI: 10.1002/anie.201409744


45. Cobalt‐Catalyzed C(sp2)H Alkoxylation of Aromatic and Olefinic Carboxamides

Zhang, Lin‐Bao; Hao, Xin‐Qi; Zhang, Shou‐Kun; Liu, Zhan‐Jiang; Zheng, Xin‐Xiang; Gong, Jun‐Fang; Niu, Jun‐Long; Song, Mao‐Ping. Angew. Chem. Int. Ed. 2015, 54, 272–275. DOI: 10.1002/anie.201409751


46. Asymmetric Dearomatization of β‐Naphthols through an Amination Reaction Catalyzed by a Chiral Phosphoric Acid

Wang, Shou‐Guo; Yin, Qin; Zhuo, Chun‐Xiang; You, Shu‐Li. Angew. Chem. Int. Ed. 2015, 54, 647–650. DOI: 10.1002/anie.201409756


47. Gold(I)‐Catalyzed Diazo Cross‐Coupling: A Selective and Ligand‐Controlled Denitrogenation/Cyclization Cascade

Xu, Guangyang; Zhu, Chenghao; Gu, Weijin; Li, Jian; Sun, Jiangtao. Angew. Chem. Int. Ed. 2015, 54, 883–887. DOI: 10.1002/anie.201409845


48. Ortho‐Quinone Methides as Reactive Intermediates in Asymmetric Brønsted Acid Catalyzed Cycloadditions with Unactivated Alkenes by Exclusive Activation of the Electrophile

Hsiao, Chien‐Chi; Raja, Sadiya; Liao, Hsuan‐Hung; Atodiresei, Iuliana; Rueping, Magnus. Angew. Chem. Int. Ed. 2015, 54, 5762–5765. DOI: 10.1002/anie.201409850


49. CO Extrusion in Homogeneous Gold Catalysis: Reactivity of Gold Acyl Species Generated through Water Addition to Gold Vinylidenes

Bucher, Janina; Stößer, Tim; Rudolph, Matthias; Rominger, Frank; Hashmi, A. Stephen K.. Angew. Chem. Int. Ed. 2015, 54, 1666–1670. DOI: 10.1002/anie.201409859


50. Remote meta‐CH Olefination of Phenylacetic Acids Directed by a Versatile U‐Shaped Template

Deng, Youqian; Yu, Jin‐Quan. Angew. Chem. Int. Ed. 2015, 54, 888–891. DOI: 10.1002/anie.201409860


51. Formal Asymmetric Catalytic Thiolation with a Bifunctional Catalyst at a Water–Oil Interface: Synthesis of Benzyl Thiols

Guo, Wengang; Wu, Bo; Zhou, Xin; Chen, Ping; Wang, Xu; Zhou, Yong‐Gui; Liu, Yan; Li, Can. Angew. Chem. Int. Ed. 2015, 54, 4522–4526. DOI: 10.1002/anie.201409894


52. An Alternative Mechanism for the Cobalt‐Catalyzed Isomerization of Terminal Alkenes to (Z)‐2‐Alkenes

Schmidt, Anastasia; Nödling, Alexander R.; Hilt, Gerhard. Angew. Chem. Int. Ed. 2015, 54, 801–804. DOI: 10.1002/anie.201409902


53. Highly Diastereoselective and Enantioselective Olefin Cyclopropanation Using Engineered Myoglobin‐Based Catalysts

Bordeaux, Melanie; Tyagi, Vikas; Fasan, Rudi. Angew. Chem. Int. Ed. 2015, 54, 1744–1748. DOI: 10.1002/anie.201409928


54. Highly Enantioselective Intramolecular 1,3‐Dipolar Cycloaddition: A Route to Piperidino‐Pyrrolizidines

Vidadala, Srinivasa Rao; Golz, Christopher; Strohmann, Carsten; Daniliuc, Constantin‐G.; Waldmann, Herbert. Angew. Chem. Int. Ed. 2015, 54, 651–655. DOI: 10.1002/anie.201409942


55. N‐Heterocyclic Carbene Catalyzed Enantioselective α‐Fluorination of Aliphatic Aldehydes and α‐Chloro Aldehydes: Synthesis of α‐Fluoro Esters, Amides, and Thioesters

Dong, Xiuqin; Yang, Wen; Hu, Weimin; Sun, Jianwei. Angew. Chem. Int. Ed. 2015, 54, 660–663. DOI: 10.1002/anie.201409961


56. Intramolecular CH Activation through Gold(I)‐Catalyzed Reaction of Iodoalkynes

Morán‐Poladura, Pablo; Rubio, Eduardo; González, José M.. Angew. Chem. Int. Ed. 2015, 54, 3052–3055. DOI: 10.1002/anie.201409970


57. Redox‐Neutral α‐Allylation of Amines by Combining Palladium Catalysis and Visible‐Light Photoredox Catalysis

Xuan, Jun; Zeng, Ting‐Ting; Feng, Zhu‐Jia; Deng, Qiao‐Hui; Chen, Jia‐Rong; Lu, Liang‐Qiu; Xiao, Wen‐Jing; Alper, Howard. Angew. Chem. Int. Ed. 2015, 54, 1625–1628. DOI: 10.1002/anie.201409999


58. Intermolecular Dynamic Kinetic Resolution Cooperatively Catalyzed by an N‐Heterocyclic Carbene and a Lewis Acid

Wu, Zijun; Li, Fangyi; Wang, Jian. Angew. Chem. Int. Ed. 2015, 54, 1629–1633. DOI: 10.1002/anie.201410030


59. The Phosphinoboration Reaction

Daley, Erika N.; Vogels, Christopher M.; Geier, Stephen J.; Decken, Andreas; Doherty, Simon; Westcott, Stephen A.. Angew. Chem. Int. Ed. 2015, 54, 2121–2125. DOI: 10.1002/anie.201410033


60. Gold‐Catalyzed Oxidative Ring Expansion of 2‐Alkynyl‐1,2‐Dihydropyridines or ‐quinolines: Highly Efficient Synthesis of Functionalized Azepine or Benzazepine Scaffolds

Chen, Ming; Chen, Yifeng; Sun, Ning; Zhao, Jidong; Liu, Yuanhong; Li, Yuxue. Angew. Chem. Int. Ed. 2015, 54, 1200–1204. DOI: 10.1002/anie.201410056


61. Tuning the Reactivity of Isocyano Group: Synthesis of Imidazoles and Imidazoliums from Propargylamines and Isonitriles in the Presence of Multiple Catalysts

Tong, Shuo; Wang, Qian; Wang, Mei‐Xiang; Zhu, Jieping. Angew. Chem. Int. Ed. 2015, 54, 1293–1297. DOI: 10.1002/anie.201410113


62. Ferrocene‐Based Planar Chiral Imidazopyridinium Salts for Catalysis

Check, Christopher T.; Jang, Ki Po; Schwamb, C. Benjamin; Wong, Alexander S.; Wang, Michael H.; Scheidt, Karl A.. Angew. Chem. Int. Ed. 2015, 54, 4264–4268. DOI: 10.1002/anie.201410118


63. Hypervalent Iodine Reagents Enable Chemoselective Deboronative/Decarboxylative Alkenylation by Photoredox Catalysis

Huang, Hanchu; Jia, Kunfang; Chen, Yiyun. Angew. Chem. Int. Ed. 2015, 54, 1881–1884. DOI: 10.1002/anie.201410176


64. Regiodivergent Addition of Phenols to Allylic Oxides: Control of 1,2‐ and 1,4‐Additions for Cyclitol Synthesis

Moschitto, Matthew J.; Vaccarello, David N.; Lewis, Chad A.. Angew. Chem. Int. Ed. 2015, 54, 2142–2145. DOI: 10.1002/anie.201410228


65. Intermolecular Enantioselective Dearomatization Reaction of β‐Naphthol Using meso‐Aziridine: A Bifunctional In Situ Generated Magnesium Catalyst

Yang, Dongxu; Wang, Linqing; Han, Fengxia; Li, Dan; Zhao, Depeng; Wang, Rui. Angew. Chem. Int. Ed. 2015, 54, 2185–2189. DOI: 10.1002/anie.201410257


66. Copper‐Catalyzed 1,2‐Addition of α‐Carbonyl Iodides to Alkynes

Xu, Tao; Hu, Xile. Angew. Chem. Int. Ed. 2015, 54, 1307–1311. DOI: 10.1002/anie.201410279


67. Nucleophilic Addition of Amines to Ruthenium Carbenes: ortho‐(Alkynyloxy)benzylamine Cyclizations towards 1,3‐Benzoxazines

González‐Rodríguez, Carlos; Suárez, José Ramón; Varela, Jesús A.; Saá, Carlos. Angew. Chem. Int. Ed. 2015, 54, 2724–2728. DOI: 10.1002/anie.201410284


68. A General and Mild Catalytic α‐Alkylation of Unactivated Esters Using Alcohols

Guo, Le; Ma, Xiaochen; Fang, Huaquan; Jia, Xiangqing; Huang, Zheng. Angew. Chem. Int. Ed. 2015, 54, 4023–4027. DOI: 10.1002/anie.201410293


69. Dinuclear Copper Intermediates in Copper(I)‐Catalyzed Azide–Alkyne Cycloaddition Directly Observed by Electrospray Ionization Mass Spectrometry

Iacobucci, Claudio; Reale, Samantha; Gal, Jean‐François; De Angelis, Francesco. Angew. Chem. Int. Ed. 2015, 54, 3065–3068. DOI: 10.1002/anie.201410301


70. From Anilines to Isatins: Oxidative Palladium‐Catalyzed Double Carbonylation of CH Bonds

Li, Wu; Duan, Zhengli; Zhang, Xueye; Zhang, Heng; Wang, Mengfan; Jiang, Ru; Zeng, Hongyao; Liu, Chao; Lei, Aiwen. Angew. Chem. Int. Ed. 2015, 54, 1893–1896. DOI: 10.1002/anie.201410321


71. Nickel‐Catalyzed Dehydrogenative Cross‐Coupling: Direct Transformation of Aldehydes into Esters and Amides

Whittaker, Aaron M.; Dong, Vy M.. Angew. Chem. Int. Ed. 2015, 54, 1312–1315. DOI: 10.1002/anie.201410322


72. Enantioselective Synthesis of α‐Aminosilanes by Copper‐Catalyzed Hydroamination of Vinylsilanes

Niljianskul, Nootaree; Zhu, Shaolin; Buchwald, Stephen L.. Angew. Chem. Int. Ed. 2015, 54, 1638–1641. DOI: 10.1002/anie.201410326


73. Rhodium(III)‐Catalyzed Cyclative Capture Approach to Diverse 1‐Aminoindoline Derivatives at Room Temperature

Zhao, Dongbing; Vásquez‐Céspedes, Suhelen; Glorius, Frank. Angew. Chem. Int. Ed. 2015, 54, 1657–1661. DOI: 10.1002/anie.201410342


74. Rhodium‐Catalyzed (5+1) Annulations Between 2‐Alkenylphenols and Allenes: A Practical Entry to 2,2‐Disubstituted 2H‐Chromenes

Casanova, Noelia; Seoane, Andrés; Mascareñas, José L.; Gulías, Moisés. Angew. Chem. Int. Ed. 2015, 54, 2374–2377. DOI: 10.1002/anie.201410350


75. Metal‐Catalyzed “On‐Demand” Production of Carbonyl Sulfide from Carbon Monoxide and Elemental Sulfur

Farrell, Wesley S.; Zavalij, Peter Y.; Sita, Lawrence R.. Angew. Chem. Int. Ed. 2015, 54, 4269–4273. DOI: 10.1002/anie.201410353


76. General Method for the Synthesis of Salicylic Acids from Phenols through Palladium‐Catalyzed Silanol‐Directed CH Carboxylation

Wang, Yang; Gevorgyan, Vladimir. Angew. Chem. Int. Ed. 2015, 54, 2255–2259. DOI: 10.1002/anie.201410375


77. Hydrogen‐Borrowing and Interrupted‐Hydrogen‐Borrowing Reactions of Ketones and Methanol Catalyzed by Iridium

Shen, Di; Poole, Darren L.; Shotton, Camilla C.; Kornahrens, Anne F.; Healy, Mark P.; Donohoe, Timothy J.. Angew. Chem. Int. Ed. 2015, 54, 1642–1645. DOI: 10.1002/anie.201410391


78. Direct α‐Arylation of Ethers through the Combination of Photoredox‐Mediated CH Functionalization and the Minisci Reaction

Jin, Jian; MacMillan, David W. C.. Angew. Chem. Int. Ed. 2015, 54, 1565–1569. DOI: 10.1002/anie.201410432


79. Orchestrated Triple CH Activation Reactions Using Two Directing Groups: Rapid Assembly of Complex Pyrazoles

Yang, Weibo; Ye, Shengqing; Fanning, Dewey; Coon, Timothy; Schmidt, Yvonne; Krenitsky, Paul; Stamos, Dean; Yu, Jin‐Quan. Angew. Chem. Int. Ed. 2015, 54, 2501–2504. DOI: 10.1002/anie.201410462


80. Palladium‐Catalyzed Intramolecular CH Difluoroalkylation: Synthesis of Substituted 3,3‐Difluoro‐2‐oxindoles

Shi, Shi‐Liang; Buchwald, Stephen L.. Angew. Chem. Int. Ed. 2015, 54, 1646–1650. DOI: 10.1002/anie.201410471


81. Synergistic Interplay of a Non‐Heme Iron Catalyst and Amino Acid Coligands in H2O2 Activation for Asymmetric Epoxidation of α‐Alkyl‐Substituted Styrenes

Cussó, Olaf; Ribas, Xavi; Lloret‐Fillol, Julio; Costas, Miquel. Angew. Chem. Int. Ed. 2015, 54, 2729–2733. DOI: 10.1002/anie.201410557


82. Synthesis of D‐ and L‐Phenylalanine Derivatives by Phenylalanine Ammonia Lyases: A Multienzymatic Cascade Process

Parmeggiani, Fabio; Lovelock, Sarah L.; Weise, Nicholas J.; Ahmed, Syed T.; Turner, Nicholas J.. Angew. Chem. Int. Ed. 2015, 54, 4608–4611. DOI: 10.1002/anie.201410670


83. Highly Enantioselective Nickel‐Catalyzed Intramolecular Reductive Cyclization of Alkynones

Fu, Wenzhen; Nie, Ming; Wang, Aizhen; Cao, Ziping; Tang, Wenjun. Angew. Chem. Int. Ed. 2015, 54, 2520–2524. DOI: 10.1002/anie.201410700


84. Catalytic Enantioselective [5+2] Cycloaddition between Oxidopyrylium Ylides and Enals under Dienamine Activation

Orue, Ane; Uria, Uxue; Reyes, Efraim; Carrillo, Luisa; Vicario, Jose L.. Angew. Chem. Int. Ed. 2015, 54, 3043–3046. DOI: 10.1002/anie.201410723


85. Regioselective Pd‐Catalyzed Methoxycarbonylation of Alkenes Using both Paraformaldehyde and Methanol as CO Surrogates

Liu, Qiang; Yuan, Kedong; Arockiam, Percia‐Beatrice; Franke, Robert; Doucet, Henri; Jackstell, Ralf; Beller, Matthias. Angew. Chem. Int. Ed. 2015, 54, 4493–4497. DOI: 10.1002/anie.201410764


86. PyBidine–Cu(OTf)2‐Catalyzed Asymmetric [3+2] Cycloaddition with Imino Esters: Harmony of Cu–Lewis Acid and Imidazolidine‐NH Hydrogen Bonding in Concerto Catalysis

Arai, Takayoshi; Ogawa, Hiroki; Awata, Atsuko; Sato, Makoto; Watabe, Megumi; Yamanaka, Masahiro. Angew. Chem. Int. Ed. 2015, 54, 1595–1599. DOI: 10.1002/anie.201410782


87. Asymmetric Dearomatization of Indoles through a Michael/Friedel–Crafts‐Type Cascade To Construct Polycyclic Spiroindolines

Zhao, Xiaohu; Liu, Xiaohua; Mei, Hongjiang; Guo, Jing; Lin, Lili; Feng, Xiaoming. Angew. Chem. Int. Ed. 2015, 54, 4032–4035. DOI: 10.1002/anie.201410814


88. Rhodium‐Catalyzed [(3+2)+2] Carbocyclization of Alkynylidenecyclopropanes with Substituted Allenes: Stereoselective Construction of Tri‐ and Tetrasubstituted Exocyclic Olefins

Evans, P. Andrew; Negru, Daniela E.; Shang, Deju. Angew. Chem. Int. Ed. 2015, 54, 4768–4772. DOI: 10.1002/anie.201410857


89. Gold‐Catalyzed Intermolecular Anti‐Markovnikov Hydroamination of Alkylidenecyclopropanes

Timmerman, Jacob C.; Robertson, Bradley D.; Widenhoefer, Ross A.. Angew. Chem. Int. Ed. 2015, 54, 2251–2254. DOI: 10.1002/anie.201410871


90. Nickel‐Catalyzed Monoarylation of Ammonia

Borzenko, Andrey; Rotta‐Loria, Nicolas L.; MacQueen, Preston M.; Lavoie, Christopher M.; McDonald, Robert; Stradiotto, Mark. Angew. Chem. Int. Ed. 2015, 54, 3773–3777. DOI: 10.1002/anie.201410875


91. Regioselective Catalytic Asymmetric C‐Alkylation of Isoxazolinones by a Base‐Free Palladacycle‐Catalyzed Direct 1,4‐Addition

Hellmuth, Tina; Frey, Wolfgang; Peters, René. Angew. Chem. Int. Ed. 2015, 54, 2788–2791. DOI: 10.1002/anie.201410933


92. Catalytic Asymmetric Diels–Alder Reaction of Quinone Imine Ketals: A Site‐Divergent Approach

Hashimoto, Takuya; Nakatsu, Hiroki; Maruoka, Keiji. Angew. Chem. Int. Ed. 2015, 54, 4617–4621. DOI: 10.1002/anie.201410957


93. Palladium(0)‐Catalyzed Iminohalogenation of Alkenes: Synthesis of 2‐Halomethyl Dihydropyrroles and Mechanistic Insights into the Alkyl Halide Bond Formation

Chen, Chen; Hou, Longlei; Cheng, Mian; Su, Jianhua; Tong, Xiaofeng. Angew. Chem. Int. Ed. 2015, 54, 3092–3096. DOI: 10.1002/anie.201410996


94. Formal anti‐Carbopalladation Reactions of Non‐Activated Alkynes: Requirements, Mechanistic Insights, and Applications

Pawliczek, Martin; Schneider, Tobias F.; Maaß, Christian; Stalke, Dietmar; Werz, Daniel B.. Angew. Chem. Int. Ed. 2015, 54, 4119–4123. DOI: 10.1002/anie.201411210


95. Synthesis of Enantioenriched 5,6‐Dihydrophenanthridine Derivatives through retro‐Carbopalladation of Chiral o‐Bromobenzylamines

Ye, Juntao; Limouni, Aurore; Zaichuk, Sonia; Lautens, Mark. Angew. Chem. Int. Ed. 2015, 54, 3116–3120. DOI: 10.1002/anie.201411276


96. The Kinetic Isotope Effect as a Probe of Spin Crossover in the CH Activation of Methane by the FeO+ Cation

Mai, Binh Khanh; Kim, Yongho. Angew. Chem. Int. Ed. 2015, 54, 3946–3951. DOI: 10.1002/anie.201411309


97. Catalytic Asymmetric Total Synthesis of (−)‐Galanthamine and (−)‐Lycoramine

Li, Lei; Yang, Qiao; Wang, Yuan; Jia, Yanxing. Angew. Chem. Int. Ed. 2015, 54, 6255–6259. DOI: 10.1002/anie.201411338


98. Visible‐Light‐Promoted Iminyl‐Radical Formation from Acyl Oximes: A Unified Approach to Pyridines, Quinolines, and Phenanthridines

Jiang, Heng; An, Xiaode; Tong, Kun; Zheng, Tianyi; Zhang, Yan; Yu, Shouyun. Angew. Chem. Int. Ed. 2015, 54, 4055–4059. DOI: 10.1002/anie.201411342


99. ZnCl2‐Promoted Asymmetric Hydrogenation of β‐Secondary‐Amino Ketones Catalyzed by a P‐Chiral Rh–Bisphosphine Complex

Hu, Qiupeng; Zhang, Zhenfeng; Liu, Yangang; Imamoto, Tsuneo; Zhang, Wanbin. Angew. Chem. Int. Ed. 2015, 54, 2260–2264. DOI: 10.1002/anie.201411384


100. Asymmetric Rhodium‐Catalyzed Addition of Thiols to Allenes: Synthesis of Branched Allylic Thioethers and Sulfones

Pritzius, Adrian B.; Breit, Bernhard. Angew. Chem. Int. Ed. 2015, 54, 3121–3125. DOI: 10.1002/anie.201411402


101. Enantioselective Enzymes by Computational Design and In Silico Screening

Wijma, Hein J.; Floor, Robert J.; Bjelic, Sinisa; Marrink, Siewert J.; Baker, David; Janssen, Dick B.. Angew. Chem. Int. Ed. 2015, 54, 3726–3730. DOI: 10.1002/anie.201411415


102. A TEMPO‐Free Copper‐Catalyzed Aerobic Oxidation of Alcohols

Xu, Boran; Lumb, Jean‐Philip; Arndtsen, Bruce A.. Angew. Chem. Int. Ed. 2015, 54, 4208–4211. DOI: 10.1002/anie.201411483


103. Cation‐Triggered Switchable Asymmetric Catalysis with Chiral Aza‐CrownPhos

Ouyang, Guang‐Hui; He, Yan‐Mei; Li, Yong; Xiang, Jun‐Feng; Fan, Qing‐Hua. Angew. Chem. Int. Ed. 2015, 54, 4334–4337. DOI: 10.1002/anie.201411593


104. Cooperative Catalysis: Enantioselective Propargylic Alkylation of Propargylic Alcohols with Enecarbamates Using Ruthenium/Phosphoramide Hybrid Catalysts

Senda, Yasushi; Nakajima, Kazunari; Nishibayashi, Yoshiaki. Angew. Chem. Int. Ed. 2015, 54, 4060–4064. DOI: 10.1002/anie.201411601


105. Electrocatalytic Water Oxidation by a Dinuclear Copper Complex in a Neutral Aqueous Solution

Su, Xiao‐Jun; Gao, Meng; Jiao, Lei; Liao, Rong‐Zhen; Siegbahn, Per E. M.; Cheng, Jin‐Pei; Zhang, Ming‐Tian. Angew. Chem. Int. Ed. 2015, 54, 4909–4914. DOI: 10.1002/anie.201411625


106. Copper‐Catalyzed Cyanomethylation of Allylic Alcohols with Concomitant 1,2‐Aryl Migration: Efficient Synthesis of Functionalized Ketones Containing an α‐Quaternary Center

Bunescu, Ala; Wang, Qian; Zhu, Jieping. Angew. Chem. Int. Ed. 2015, 54, 3132–3135. DOI: 10.1002/anie.201411657


107. Zinc(II)‐Catalyzed Intermolecular Hydrative Aldol Reactions of 2‐En‐1‐ynamides with Aldehydes and Water to form Branched Aldol Products Regio‐ and Stereoselectively

Jadhav, Appaso Mahadev; Pagar, Vinayak Vishnu; Huple, Deepak B.; Liu, Rai‐Shung. Angew. Chem. Int. Ed. 2015, 54, 3812–3816. DOI: 10.1002/anie.201411689


108. Carboxylic Acids as Traceless Directing Groups for the Rhodium(III)‐Catalyzed Decarboxylative CH Arylation of Thiophenes

Zhang, Yuanfei; Zhao, Huaiqing; Zhang, Min; Su, Weiping. Angew. Chem. Int. Ed. 2015, 54, 3817–3821. DOI: 10.1002/anie.201411701


109. Oxidative CH Bond Functionalization and Ring Expansion with TMSCHN2: A Copper(I)‐Catalyzed Approach to Dibenzoxepines and Dibenzoazepines

Stopka, Tobias; Marzo, Leyre; Zurro, Mercedes; Janich, Simon; Würthwein, Ernst‐Ulrich; Daniliuc, Constantin G.; Alemán, José; Mancheño, Olga García. Angew. Chem. Int. Ed. 2015, 54, 5049–5053. DOI: 10.1002/anie.201411726


110. Stereoselective Nickel‐Catalyzed [2+2] Cycloadditions of Ene‐Allenes

Noucti, Njamkou N.; Alexanian, Erik J.. Angew. Chem. Int. Ed. 2015, 54, 5447–5450. DOI: 10.1002/anie.201411737


111. Manganese‐Catalyzed Synthesis of cis‐β‐Amino Acid Esters through Organometallic CH Activation of Ketimines

Liu, Weiping; Zell, Daniel; John, Michael; Ackermann, Lutz. Angew. Chem. Int. Ed. 2015, 54, 4092–4096. DOI: 10.1002/anie.201411808


112. Enantioselective Palladium‐Catalyzed Dearomative Cyclization for the Efficient Synthesis of Terpenes and Steroids

Du, Kang; Guo, Pan; Chen, Yuan; Cao, Zhen; Wang, Zheng; Tang, Wenjun. Angew. Chem. Int. Ed. 2015, 54, 3033–3037. DOI: 10.1002/anie.201411817


113. Direct Catalytic Enantio‐ and Diastereoselective Ketone Aldol Reactions of Isocyanoacetates

de la Campa, Raquel; Ortín, Irene; Dixon, Darren J.. Angew. Chem. Int. Ed. 2015, 54, 4895–4898. DOI: 10.1002/anie.201411852


114. Catalytic Asymmetric Hydroalkenylation of Vinylarenes: Electronic Effects of Substrates and Chiral N‐Heterocyclic Carbene Ligands

Ho, Chun‐Yu; Chan, Chun‐Wa; He, Lisi. Angew. Chem. Int. Ed. 2015, 54, 4512–4516. DOI: 10.1002/anie.201411882


115. Iron‐Catalyzed Asymmetric Hydrosilylation of 1,1‐Disubstituted Alkenes

Chen, Jianhui; Cheng, Biao; Cao, Minyi; Lu, Zhan. Angew. Chem. Int. Ed. 2015, 54, 4661–4664. DOI: 10.1002/anie.201411884


116. An Unusual Terpene Cyclization Mechanism Involving a Carbon–Carbon Bond Rearrangement

Meguro, Ayuko; Motoyoshi, Yudai; Teramoto, Kazuya; Ueda, Shota; Totsuka, Yusuke; Ando, Yumi; Tomita, Takeo; Kim, Seung‐Young; Kimura, Tomoyuki; Igarashi, Masayuki; Sawa, Ryuichi; Shinada, Tetsuro; Nishiyama, Makoto; Kuzuyama, Tomohisa. Angew. Chem. Int. Ed. 2015, 54, 4353–4356. DOI: 10.1002/anie.201411923


117. Enantioselective Desymmetrization of Prochiral Cyclohexanones by Organocatalytic Intramolecular Michael Additions to α,β‐Unsaturated Esters

Gammack Yamagata, Adam D.; Datta, Swarup; Jackson, Kelvin E.; Stegbauer, Linus; Paton, Robert S.; Dixon, Darren J.. Angew. Chem. Int. Ed. 2015, 54, 4899–4903. DOI: 10.1002/anie.201411924


118. Cobalt‐Catalyzed Negishi Cross‐Coupling Reactions of (Hetero)Arylzinc Reagents with Primary and Secondary Alkyl Bromides and Iodides

Hammann, Jeffrey M.; Haas, Diana; Knochel, Paul. Angew. Chem. Int. Ed. 2015, 54, 4478–4481. DOI: 10.1002/anie.201411960


119. Cobalt(III)‐Catalyzed Directed CH Coupling with Diazo Compounds: Straightforward Access towards Extended π‐Systems

Zhao, Dongbing; Kim, Ju Hyun; Stegemann, Linda; Strassert, Cristian A.; Glorius, Frank. Angew. Chem. Int. Ed. 2015, 54, 4508–4511. DOI: 10.1002/anie.201411994


120. Nickel‐Catalyzed Monofluoromethylation of Aryl Boronic Acids

Su, Yi‐Ming; Feng, Guang‐Shou; Wang, Zhen‐Yu; Lan, Quan; Wang, Xi‐Sheng. Angew. Chem. Int. Ed. 2015, 54, 6003–6007. DOI: 10.1002/anie.201412026


121. Highly Stereoselective Synthesis of Natural‐Product‐Like Hybrids by an Organocatalytic/Multicomponent Reaction Sequence

Echemendía, Radell; de La Torre, Alexander F.; Monteiro, Julia L.; Pila, Michel; Corrêa, Arlene G.; Westermann, Bernhard; Rivera, Daniel G.; Paixão, Márcio W.. Angew. Chem. Int. Ed. 2015, 54, 7621–7625. DOI: 10.1002/anie.201412074


122. Temperature‐Controlled Bidirectional Enantioselectivity in a Dynamic Catalyst for Asymmetric Hydrogenation

Storch, Golo; Trapp, Oliver. Angew. Chem. Int. Ed. 2015, 54, 3580–3586. DOI: 10.1002/anie.201412098


123. A Metal–Ligand Cooperative Pathway for Intermolecular Oxa‐Michael Additions to Unsaturated Nitriles

Perdriau, Sébastien; Zijlstra, Douwe S.; Heeres, Hero J.; de Vries, Johannes G.; Otten, Edwin. Angew. Chem. Int. Ed. 2015, 54, 4236–4240. DOI: 10.1002/anie.201412110


124. Aminomethylation of Enals through Carbene and Acid Cooperative Catalysis: Concise Access to β2‐Amino Acids

Xu, Jianfeng; Chen, Xingkuan; Wang, Ming; Zheng, Pengcheng; Song, Bao‐An; Chi, Yonggui Robin. Angew. Chem. Int. Ed. 2015, 54, 5161–5165. DOI: 10.1002/anie.201412132


125. OH‐Directed Alkynylation of 2‐Vinylphenols with Ethynyl Benziodoxolones: A Fast Access to Terminal 1,3‐Enynes

Finkbeiner, Peter; Kloeckner, Ulrich; Nachtsheim, Boris J.. Angew. Chem. Int. Ed. 2015, 54, 4949–4952. DOI: 10.1002/anie.201412148


126. Efficient Cu‐catalyzed Atom Transfer Radical Addition Reactions of Fluoroalkylsulfonyl Chlorides with Electron‐deficient Alkenes Induced by Visible Light

Tang, Xiao‐Jun; Dolbier, William R.. Angew. Chem. Int. Ed. 2015, 54, 4246–4249. DOI: 10.1002/anie.201412199


127. Ligand‐Promoted Oxidative Cross‐Coupling of Aryl Boronic Acids and Aryl Silanes by Palladium Catalysis

Yu, Jingxun; Liu, Jun; Shi, Guangfa; Shao, Changdong; Zhang, Yanghui. Angew. Chem. Int. Ed. 2015, 54, 4079–4082. DOI: 10.1002/anie.201412288


128. Phosphine‐Catalyzed Remote β‐CH Functionalization of Amines Triggered by Trifluoromethylation of Alkenes: One‐Pot Synthesis of Bistrifluoromethylated Enamides and Oxazoles

Yu, Peng; Zheng, Sheng‐Cai; Yang, Ning‐Yuan; Tan, Bin; Liu, Xin‐Yuan. Angew. Chem. Int. Ed. 2015, 54, 4041–4045. DOI: 10.1002/anie.201412310


129. Copper‐Catalyzed Intermolecular Carboetherification of Unactivated Alkenes by Alkyl Nitriles and Alcohols

Chatalova‐Sazepin, Claire; Wang, Qian; Sammis, Glenn M.; Zhu, Jieping. Angew. Chem. Int. Ed. 2015, 54, 5443–5446. DOI: 10.1002/anie.201412357


130. Catalytic Asymmetric Mannich‐Type Reaction of N‐Alkylidene‐α‐Aminoacetonitrile with Ketimines

Lin, Shaoquan; Kawato, Yuji; Kumagai, Naoya; Shibasaki, Masakatsu. Angew. Chem. Int. Ed. 2015, 54, 5183–5186. DOI: 10.1002/anie.201412377


131. Copper(I)‐Catalyzed Alkylation of Polyfluoroarenes through Direct CH Bond Functionalization

Xu, Shuai; Wu, Guojiao; Ye, Fei; Wang, Xi; Li, Huan; Zhao, Xia; Zhang, Yan; Wang, Jianbo. Angew. Chem. Int. Ed. 2015, 54, 4669–4672. DOI: 10.1002/anie.201412450


132. Catalytic Upgrading of Biomass‐Derived Methyl Ketones to Liquid Transportation Fuel Precursors by an Organocatalytic Approach

Sankaranarayanapillai, Shylesh; Sreekumar, Sanil; Gomes, Joseph; Grippo, Adam; Arab, George E.; Head‐Gordon, Martin; Toste, F. Dean; Bell, Alexis T.. Angew. Chem. Int. Ed. 2015, 54, 4673–4677. DOI: 10.1002/anie.201412470


133. A Concise and Scalable Strategy for the Total Synthesis of Dictyodendrin B Based on Sequential CH Functionalization

Pitts, Andrew K.; O'Hara, Fionn; Snell, Robert H.; Gaunt, Matthew J.. Angew. Chem. Int. Ed. 2015, 54, 5451–5455. DOI: 10.1002/anie.201500067


134. Redox Tuning of a Direct Asymmetric Aldol Reaction

Zhang, Qiying; Cui, Xiuling; Zhang, Long; Luo, Sanzhong; Wang, Hui; Wu, Yangjie. Angew. Chem. Int. Ed. 2015, 54, 5210–5213. DOI: 10.1002/anie.201500070


135. Palladium‐Catalyzed Enantioselective CH Arylation for the Synthesis of P‐Stereogenic Compounds

Lin, Zi‐Qi; Wang, Wei‐Zhen; Yan, Shao‐Bai; Duan, Wei‐Liang. Angew. Chem. Int. Ed. 2015, 54, 6265–6269. DOI: 10.1002/anie.201500201


136. Catalytic Asymmetric Inverse‐Electron‐Demand Oxa‐Diels–Alder Reaction of In Situ Generated ortho‐Quinone Methides with 3‐Methyl‐2‐Vinylindoles

Zhao, Jia‐Jia; Sun, Si‐Bing; He, Sai‐Huan; Wu, Qiong; Shi, Feng. Angew. Chem. Int. Ed. 2015, 54, 5460–5464. DOI: 10.1002/anie.201500215


137. The Organocatalytic Asymmetric Prins Cyclization

Tsui, Gavin Chit; Liu, Luping; List, Benjamin. Angew. Chem. Int. Ed. 2015, 54, 7703–7706. DOI: 10.1002/anie.201500219


138. Regio‐ and Stereoselective Conjugate Addition of Aldehydes to β‐Tosyl Enones under the Catalysis of a Binaphthyl‐Modified Chiral Amine

Kano, Taichi; Sugimoto, Hisashi; Maruyama, Hiroki; Maruoka, Keiji. Angew. Chem. Int. Ed. 2015, 54, 8462–8465. DOI: 10.1002/anie.201500225


139. Ruthenium‐Catalyzed CC Coupling of Fluorinated Alcohols with Allenes: Dehydrogenation at the Energetic Limit of β‐Hydride Elimination

Sam, Brannon; Luong, Tom; Krische, Michael J.. Angew. Chem. Int. Ed. 2015, 54, 5465–5469. DOI: 10.1002/anie.201500238


140. Phosphahelicenes in Asymmetric Organocatalysis: [3+2] Cyclizations of γ‐Substituted Allenes and Electron‐Poor Olefins

Gicquel, Maxime; Zhang, Yang; Aillard, Paul; Retailleau, Pascal; Voituriez, Arnaud; Marinetti, Angela. Angew. Chem. Int. Ed. 2015, 54, 5470–5473. DOI: 10.1002/anie.201500299


141. Gold‐Catalyzed Cycloaddition Reactions of Ethyl Diazoacetate, Nitrosoarenes, and Vinyldiazo Carbonyl Compounds: Synthesis of Isoxazolidine and Benzo[b]azepine Derivatives

Pagar, Vinayak Vishnu; Liu, Rai‐Shung. Angew. Chem. Int. Ed. 2015, 54, 4923–4926. DOI: 10.1002/anie.201500340


142. Regioselective Acceptorless Dehydrogenative Coupling of N‐Heterocycles toward Functionalized Quinolines, Phenanthrolines, and Indoles

Talwar, Dinesh; Gonzalez‐de‐Castro, Angela; Li, Ho Yin; Xiao, Jianliang. Angew. Chem. Int. Ed. 2015, 54, 5223–5227. DOI: 10.1002/anie.201500346


143. Efficient Asymmetric Synthesis of Structurally Diverse P‐Stereogenic Phosphinamides for Catalyst Design

Han, Zhengxu S.; Zhang, Li; Xu, Yibo; Sieber, Joshua D.; Marsini, Maurice A.; Li, Zhibin; Reeves, Jonathan T.; Fandrick, Keith R.; Patel, Nitinchandra D.; Desrosiers, Jean‐Nicolas; Qu, Bo; Chen, Anji; Rudzinski, DiAndra M.; Samankumara, Lalith P.; Ma, Shengli; Grinberg, Nelu; Roschangar, Frank; Yee, Nathan K.; Wang, Guijun; Song, Jinhua J.; Senanayake, Chris H.. Angew. Chem. Int. Ed. 2015, 54, 5474–5477. DOI: 10.1002/anie.201500350


144. Targeted Fluorination with the Fluoride Ion by Manganese‐Catalyzed Decarboxylation

Huang, Xiongyi; Liu, Wei; Hooker, Jacob M.; Groves, John T.. Angew. Chem. Int. Ed. 2015, 54, 5241–5245. DOI: 10.1002/anie.201500399


145. Nickel‐Catalyzed Amination of Aryl Chlorides with Ammonia or Ammonium Salts

Green, Rebecca A.; Hartwig, John F.. Angew. Chem. Int. Ed. 2015, 54, 3768–3772. DOI: 10.1002/anie.201500404


146. A Mild and Efficient CH2‐Extrusion Reaction for the Enantiospecific Synthesis of Highly Configurationally Stable Tröger Bases

Pujari, Sandip A.; Besnard, Céline; Bürgi, Thomas; Lacour, Jérôme. Angew. Chem. Int. Ed. 2015, 54, 7520–7523. DOI: 10.1002/anie.201500435


147. Enantioselective Synthesis of Macrocyclic Heterobiaryl Derivatives of Molecular Asymmetry by Molybdenum‐Catalyzed Asymmetric Ring‐Closing Metathesis

Okayama, Yoichi; Tsuji, Satoru; Toyomori, Yuka; Mori, Atsunori; Arae, Sachie; Wu, Wei‐Yi; Takahashi, Tamotsu; Ogasawara, Masamichi. Angew. Chem. Int. Ed. 2015, 54, 4927–4931. DOI: 10.1002/anie.201500459


148. Cerium(IV)‐Driven Water Oxidation Catalyzed by a Manganese(V)–Nitrido Complex

Ma, Li; Wang, Qian; Man, Wai‐Lun; Kwong, Hoi‐Ki; Ko, Chi‐Chiu; Lau, Tai‐Chu. Angew. Chem. Int. Ed. 2015, 54, 5246–5249. DOI: 10.1002/anie.201500507


149. Cooperative Bond Activation and Catalytic Reduction of Carbon Dioxide at a Group 13 Metal Center

Abdalla, Joseph A. B.; Riddlestone, Ian M.; Tirfoin, Rémi; Aldridge, Simon. Angew. Chem. Int. Ed. 2015, 54, 5098–5102. DOI: 10.1002/anie.201500570


150. Palladium‐Catalyzed Vicinal Amino Alcohols Synthesis from Allyl Amines by In Situ Tether Formation and Carboetherification

Orcel, Ugo; Waser, Jerome. Angew. Chem. Int. Ed. 2015, 54, 5250–5254. DOI: 10.1002/anie.201500636


151. Total Synthesis of Ellagitannins through Regioselective Sequential Functionalization of Unprotected Glucose

Takeuchi, Hironori; Mishiro, Kenji; Ueda, Yoshihiro; Fujimori, Yusuke; Furuta, Takumi; Kawabata, Takeo. Angew. Chem. Int. Ed. 2015, 54, 6177–6180. DOI: 10.1002/anie.201500700


152. Organocatalytic Enantioselective Oxidative CH Alkenylation and Arylation of N‐Carbamoyl Tetrahydropyridines and Tetrahydro‐β‐carbolines

Liu, Xigong; Meng, Zhilin; Li, Chengkun; Lou, Hongxiang; Liu, Lei. Angew. Chem. Int. Ed. 2015, 54, 6012–6015. DOI: 10.1002/anie.201500703


153. Enantioselective Palladium(0)‐Catalyzed Nazarov‐Type Cyclization

Kitamura, Kei; Shimada, Naoyuki; Stewart, Craig; Atesin, Abdurrahman C.; Ateşin, Tülay A.; Tius, Marcus A.. Angew. Chem. Int. Ed. 2015, 54, 6288–6291. DOI: 10.1002/anie.201500881


154. Alkyl Aryl Ether Bond Formation with PhenoFluor

Shen, Xiao; Neumann, Constanze N.; Kleinlein, Claudia; Goldberg, Nathaniel W.; Ritter, Tobias. Angew. Chem. Int. Ed. 2015, 54, 5662–5665. DOI: 10.1002/anie.201500902


155. Design, Synthesis, and Application of a Chiral Sulfinamide Phosphine Catalyst for the Enantioselective Intramolecular Rauhut–Currier Reaction

Su, Xiao; Zhou, Wei; Li, Yangyan; Zhang, Junliang. Angew. Chem. Int. Ed. 2015, 54, 6874–6877. DOI: 10.1002/anie.201500907


156. Assembly of Fluorinated Quaternary Stereogenic Centers through Catalytic Enantioselective Detrifluoroacetylative Aldol Reactions

Xie, Chen; Wu, Lingmin; Han, Jianlin; Soloshonok, Vadim A.; Pan, Yi. Angew. Chem. Int. Ed. 2015, 54, 6019–6023. DOI: 10.1002/anie.201500908


157. Highly Efficient Ruthenium‐Catalyzed N‐Formylation of Amines with H2 and CO2

Zhang, Lei; Han, Zhaobin; Zhao, Xiaoyu; Wang, Zheng; Ding, Kuiling. Angew. Chem. Int. Ed. 2015, 54, 6186–6189. DOI: 10.1002/anie.201500939


158. Asymmetric Total Synthesis of Mycoleptodiscin A

Zhou, Shupeng; Chen, Hao; Luo, Yijie; Zhang, Wenhao; Li, Ang. Angew. Chem. Int. Ed. 2015, 54, 6878–6882. DOI: 10.1002/anie.201501021


159. Palladium(II)/Brønsted Acid‐Catalyzed Enantioselective Oxidative Carbocyclization–Borylation of Enallenes

Jiang, Tuo; Bartholomeyzik, Teresa; Mazuela, Javier; Willersinn, Jochen; Bäckvall, Jan‐E.. Angew. Chem. Int. Ed. 2015, 54, 6024–6027. DOI: 10.1002/anie.201501048


160. Aromatic Amide‐Derived Non‐Biaryl Atropisomers as Highly Efficient Ligands in Silver‐Catalyzed Asymmetric Cycloaddition Reactions

Bai, Xing‐Feng; Song, Tao; Xu, Zheng; Xia, Chun‐Gu; Huang, Wei‐Sheng; Xu, Li‐Wen. Angew. Chem. Int. Ed. 2015, 54, 5255–5259. DOI: 10.1002/anie.201501100


161. Photooxidizing Chromium Catalysts for Promoting Radical Cation Cycloadditions

Stevenson, Susan M.; Shores, Matthew P.; Ferreira, Eric M.. Angew. Chem. Int. Ed. 2015, 54, 6506–6510. DOI: 10.1002/anie.201501220


162. Organocatalytic Asymmetric Addition of Naphthols and Electron‐Rich Phenols to Isatin‐Derived Ketimines: Highly Enantioselective Construction of Tetrasubstituted Stereocenters

Montesinos‐Magraner, Marc; Vila, Carlos; Cantón, Rubén; Blay, Gonzalo; Fernández, Isabel; Muñoz, M. Carmen; Pedro, José R.. Angew. Chem. Int. Ed. 2015, 54, 6320–6324. DOI: 10.1002/anie.201501273


163. Catalytic Enantioselective Synthesis of N,Cα,Cα‐Trisubstituted α‐Amino Acid Derivatives Using 1H‐Imidazol‐4(5H)‐ones as Key Templates

Etxabe, Julen; Izquierdo, Joseba; Landa, Aitor; Oiarbide, Mikel; Palomo, Claudio. Angew. Chem. Int. Ed. 2015, 54, 6883–6886. DOI: 10.1002/anie.201501275


164. Palladium‐Catalyzed CH Activation of N‐Allyl Imines: Regioselective Allylic Alkylations to Deliver Substituted Aza‐1,3‐Dienes

Trost, Barry M.; Mahapatra, Subham; Hansen, Martin. Angew. Chem. Int. Ed. 2015, 54, 6032–6036. DOI: 10.1002/anie.201501322


165. Synthesis of Each Enantiomer of Rocaglamide by Means of a Palladium(0)‐Catalyzed Nazarov‐Type Cyclization

Zhou, Zhe; Tius, Marcus A.. Angew. Chem. Int. Ed. 2015, 54, 6037–6040. DOI: 10.1002/anie.201501374


166. From Carbanions to Organometallic Compounds: Quantification of Metal Ion Effects on Nucleophilic Reactivities

Corral‐Bautista, Francisco; Klier, Lydia; Knochel, Paul; Mayr, Herbert. Angew. Chem. Int. Ed. 2015, 54, 12497–12500. DOI: 10.1002/anie.201501385


167. Catalytic Enantioselective Intramolecular Aza‐Diels–Alder Reactions

Min, Chang; Lin, Chih‐Tsung; Seidel, Daniel. Angew. Chem. Int. Ed. 2015, 54, 6608–6612. DOI: 10.1002/anie.201501536


168. Photoredox‐Catalyzed Reductive Coupling of Aldehydes, Ketones, and Imines with Visible Light

Nakajima, Masaki; Fava, Eleonora; Loescher, Sebastian; Jiang, Zhen; Rueping, Magnus. Angew. Chem. Int. Ed. 2015, 54, 8828–8832. DOI: 10.1002/anie.201501556


169. Concise and Practical Asymmetric Synthesis of a Challenging Atropisomeric HIV Integrase Inhibitor

Fandrick, Keith R.; Li, Wenjie; Zhang, Yongda; Tang, Wenjun; Gao, Joe; Rodriguez, Sonia; Patel, Nitinchandra D.; Reeves, Diana C.; Wu, Jiang‐Ping; Sanyal, Sanjit; Gonnella, Nina; Qu, Bo; Haddad, Nizar; Lorenz, Jon C.; Sidhu, Kanwar; Wang, June; Ma, Shengli; Grinberg, Nelu; Lee, Heewon; Tsantrizos, Youla; Poupart, Marc‐André; Busacca, Carl A.; Yee, Nathan K.; Lu, Bruce Z.; Senanayake, Chris H.. Angew. Chem. Int. Ed. 2015, 54, 7144–7148. DOI: 10.1002/anie.201501575


170. Direct Catalytic Asymmetric Aldol Reaction of an α‐Azido Amide

Weidner, Karin; Sun, Zhongdong; Kumagai, Naoya; Shibasaki, Masakatsu. Angew. Chem. Int. Ed. 2015, 54, 6236–6240. DOI: 10.1002/anie.201501607


171. Palladium‐Catalyzed Asymmetric Reductive Heck Reaction of Aryl Halides

Yue, Guizhou; Lei, Kaining; Hirao, Hajime; Zhou, Jianrong (Steve). Angew. Chem. Int. Ed. 2015, 54, 6531–6535. DOI: 10.1002/anie.201501712


172. Hydroxy‐Directed, Fluoride‐Catalyzed Epoxide Hydrosilylation for the Synthesis of 1,4‐Diols

Zhang, Yong‐Qiang; Funken, Nico; Winterscheid, Peter; Gansäuer, Andreas. Angew. Chem. Int. Ed. 2015, 54, 6931–6934. DOI: 10.1002/anie.201501729


173. Michael Addition Catalyzed by Chiral Secondary Amine Phosphoramide Using Fluorinated Silyl Enol Ethers: Formation of Quaternary Carbon Stereocenters

Yu, Jin‐Sheng; Liao, Fu‐Min; Gao, Wei‐Ming; Liao, Kui; Zuo, Run‐Lin; Zhou, Jian. Angew. Chem. Int. Ed. 2015, 54, 7381–7385. DOI: 10.1002/anie.201501747


174. Regio‐ and Enantioselective Synthesis of N‐Substituted Pyrazoles by Rhodium‐Catalyzed Asymmetric Addition to Allenes

Haydl, Alexander M.; Xu, Kun; Breit, Bernhard. Angew. Chem. Int. Ed. 2015, 54, 7149–7153. DOI: 10.1002/anie.201501758


175. Brønsted Acid Catalyzed Asymmetric Hydroamination of Alkenes: Synthesis of Pyrrolidines Bearing a Tetrasubstituted Carbon Stereocenter

Lin, Jin‐Shun; Yu, Peng; Huang, Lin; Zhang, Pan; Tan, Bin; Liu, Xin‐Yuan. Angew. Chem. Int. Ed. 2015, 54, 7847–7851. DOI: 10.1002/anie.201501762


176. Asymmetric Synthesis of 1,3‐Butadienyl‐2‐carbinols by the Homoallenylboration of Aldehydes with a Chiral Phosphoric Acid Catalyst

Huang, Yiyong; Yang, Xing; Lv, Zongchao; Cai, Chen; Kai, Cheng; Pei, Yong; Feng, Yu. Angew. Chem. Int. Ed. 2015, 54, 7299–7302. DOI: 10.1002/anie.201501832


177. Iridium‐Catalyzed Enantioselective Allylic Alkylation with Functionalized Organozinc Bromides

Hamilton, James Y.; Sarlah, David; Carreira, Erick M.. Angew. Chem. Int. Ed. 2015, 54, 7644–7647. DOI: 10.1002/anie.201501851


178. Trifluoromethylchlorosulfonylation of Alkenes: Evidence for an Inner‐Sphere Mechanism by a Copper Phenanthroline Photoredox Catalyst

Bagal, Dattatraya B.; Kachkovskyi, Georgiy; Knorn, Matthias; Rawner, Thomas; Bhanage, Bhalchandra M.; Reiser, Oliver. Angew. Chem. Int. Ed. 2015, 54, 6999–7002. DOI: 10.1002/anie.201501880


179. Organocatalytic, Asymmetric Eliminative [4+2] Cycloaddition of Allylidene Malononitriles with Enals: Rapid Entry to Cyclohexadiene‐Embedding Linear and Angular Polycycles

Brindani, Nicoletta; Rassu, Gloria; Dell'Amico, Luca; Zambrano, Vincenzo; Pinna, Luigi; Curti, Claudio; Sartori, Andrea; Battistini, Lucia; Casiraghi, Giovanni; Pelosi, Giorgio; Greco, Daniela; Zanardi, Franca. Angew. Chem. Int. Ed. 2015, 54, 7386–7390. DOI: 10.1002/anie.201501894


180. Merging Photoredox and Nickel Catalysis: The Direct Synthesis of Ketones by the Decarboxylative Arylation of α‐Oxo Acids

Chu, Lingling; Lipshultz, Jeffrey M.; MacMillan, David W. C.. Angew. Chem. Int. Ed. 2015, 54, 7929–7933. DOI: 10.1002/anie.201501908


181. Direct Synthesis of Chiral Allenoates from the Asymmetric CH Insertion of α‐Diazoesters into Terminal Alkynes

Tang, Yu; Chen, Quangang; Liu, Xiaohua; Wang, Gang; Lin, Lili; Feng, Xiaoming. Angew. Chem. Int. Ed. 2015, 54, 9512–9516. DOI: 10.1002/anie.201501918


182. Cationic Titanocene(III) Complexes for Catalysis in Single‐Electron Steps

Gansäuer, Andreas; Hildebrandt, Sven; Michelmann, Antonius; Dahmen, Tobias; von Laufenberg, Daniel; Kube, Christian; Fianu, Godfred D.; Flowers, Robert A.. Angew. Chem. Int. Ed. 2015, 54, 7003–7006. DOI: 10.1002/anie.201501955


183. Enantioselective Syntheses of Heteroyohimbine Natural Products: A Unified Approach through Cooperative Catalysis

Younai, Ashkaan; Zeng, Bi‐Shun; Meltzer, Herbert Y.; Scheidt, Karl A.. Angew. Chem. Int. Ed. 2015, 54, 6900–6904. DOI: 10.1002/anie.201502011


184. Total Synthesis of Diterpenoid Steenkrotin A

Pan, Saiyong; Xuan, Jun; Gao, Beiling; Zhu, An; Ding, Hanfeng. Angew. Chem. Int. Ed. 2015, 54, 6905–6908. DOI: 10.1002/anie.201502034


185. Palladium(0)/PAr3‐Catalyzed Intermolecular Amination of C(sp3)H Bonds: Synthesis of β‐Amino Acids

He, Jian; Shigenari, Toshihiko; Yu, Jin‐Quan. Angew. Chem. Int. Ed. 2015, 54, 6545–6549. DOI: 10.1002/anie.201502075


186. Rhodium‐Catalyzed Hydroformylation of 1,1‐Disubstituted Allenes Employing the Self‐Assembling 6‐DPPon System

Köpfer, Alexander; Breit, Bernhard. Angew. Chem. Int. Ed. 2015, 54, 6913–6917. DOI: 10.1002/anie.201502086


187. Noncovalent Lone Pair⋅⋅⋅(No‐π!)‐Heteroarene Interactions: The Janus‐Faced Hydroxy Group

Pavlakos, Ilias; Arif, Tanzeel; Aliev, Abil E.; Motherwell, William B.; Tizzard, Graham J.; Coles, Simon J.. Angew. Chem. Int. Ed. 2015, 54, 8169–8174. DOI: 10.1002/anie.201502103


188. Majority‐Rules‐Type Helical Poly(quinoxaline‐2,3‐diyl)s as Highly Efficient Chirality‐Amplification Systems for Asymmetric Catalysis

Ke, Yuan‐Zhen; Nagata, Yuuya; Yamada, Tetsuya; Suginome, Michinori. Angew. Chem. Int. Ed. 2015, 54, 9333–9337. DOI: 10.1002/anie.201502209


189. Versatile In Situ Generated N‐Boc‐Imines: Application to Phase‐Transfer‐Catalyzed Asymmetric Mannich‐Type Reactions

Kano, Taichi; Kobayashi, Ryohei; Maruoka, Keiji. Angew. Chem. Int. Ed. 2015, 54, 8471–8474. DOI: 10.1002/anie.201502215


190. Rhodium(II)‐Catalyzed Enantioselective Synthesis of Troponoids

Murarka, Sandip; Jia, Zhi‐Jun; Merten, Christian; Daniliuc, Constantin‐G.; Antonchick, Andrey P.; Waldmann, Herbert. Angew. Chem. Int. Ed. 2015, 54, 7653–7656. DOI: 10.1002/anie.201502233


191. Enantioselective Synthesis of Pyrrole‐Based Spiro‐ and Polycyclic Derivatives by Iridium‐Catalyzed Asymmetric Allylic Dearomatization and Controllable Migration Reactions

Zhuo, Chun‐Xiang; Cheng, Qiang; Liu, Wen‐Bo; Zhao, Qiang; You, Shu‐Li. Angew. Chem. Int. Ed. 2015, 54, 8475–8479. DOI: 10.1002/anie.201502259


192. Scalable Synthesis of the Potent HIV Inhibitor BMS‐986001 by Non‐Enzymatic Dynamic Kinetic Asymmetric Transformation (DYKAT)

Ortiz, Adrian; Benkovics, Tamas; Beutner, Gregory L.; Shi, Zhongping; Bultman, Michael; Nye, Jeffrey; Sfouggatakis, Chris; Kronenthal, David R.. Angew. Chem. Int. Ed. 2015, 54, 7185–7188. DOI: 10.1002/anie.201502290


193. Pd‐Catalyzed Regioselective Activation of gem‐Difluorinated Cyclopropanes: A Highly Efficient Approach to 2‐Fluorinated Allylic Scaffolds

Xu, Jun; Ahmed, Ebrahim‐Alkhalil; Xiao, Bin; Lu, Qian‐Qian; Wang, Yun‐Long; Yu, Chu‐Guo; Fu, Yao. Angew. Chem. Int. Ed. 2015, 54, 8231–8235. DOI: 10.1002/anie.201502308


194. Highly Stereoselective Intermolecular Haloetherification and Haloesterification of Allyl Amides

Soltanzadeh, Bardia; Jaganathan, Arvind; Staples, Richard J.; Borhan, Babak. Angew. Chem. Int. Ed. 2015, 54, 9517–9522. DOI: 10.1002/anie.201502341


195. Dual Hypervalent Iodine(III) Reagents and Photoredox Catalysis Enable Decarboxylative Ynonylation under Mild Conditions

Huang, Hanchu; Zhang, Guojin; Chen, Yiyun. Angew. Chem. Int. Ed. 2015, 54, 7872–7876. DOI: 10.1002/anie.201502369


196. Rhodium‐Catalyzed [3+2+2] and [2+2+2] Cycloadditions of Two Alkynes with Cyclopropylideneacetamides

Yoshida, Tomoka; Tajima, Yuki; Kobayashi, Masayuki; Masutomi, Koji; Noguchi, Keiichi; Tanaka, Ken. Angew. Chem. Int. Ed. 2015, 54, 8241–8244. DOI: 10.1002/anie.201502505


197. Rhodium‐Catalyzed Enantioselective Intramolecular CH Silylation for the Syntheses of Planar‐Chiral Metallocene Siloles

Zhang, Qing‐Wei; An, Kun; Liu, Li‐Chuan; Yue, Yuan; He, Wei. Angew. Chem. Int. Ed. 2015, 54, 6918–6921. DOI: 10.1002/anie.201502548


198. Enantioselective Construction of 3‐Hydroxypiperidine Scaffolds by Sequential Action of Light and Rhodium upon N‐Allylglyoxylamides

Ishida, Naoki; Nečas, David; Masuda, Yusuke; Murakami, Masahiro. Angew. Chem. Int. Ed. 2015, 54, 7418–7421. DOI: 10.1002/anie.201502584


199. Design of New Ligands for the Palladium‐Catalyzed Arylation of α‐Branched Secondary Amines

Park, Nathaniel H.; Vinogradova, Ekaterina V.; Surry, David S.; Buchwald, Stephen L.. Angew. Chem. Int. Ed. 2015, 54, 8259–8262. DOI: 10.1002/anie.201502626


200. Highly Enantioselective Nucleophilic Dearomatization of Pyridines by Anion‐Binding Catalysis

García Mancheño, Olga; Asmus, Sören; Zurro, Mercedes; Fischer, Theresa. Angew. Chem. Int. Ed. 2015, 54, 8823–8827. DOI: 10.1002/anie.201502708


201. Organocatalytic Activation of the Leaving Group in the Intramolecular Asymmetric SN2′ Reaction

Kuroda, Yusuke; Harada, Shingo; Oonishi, Akinori; Yamaoka, Yousuke; Yamada, Ken‐ichi; Takasu, Kiyosei. Angew. Chem. Int. Ed. 2015, 54, 8263–8266. DOI: 10.1002/anie.201502831


202. Development of Chiral Spiro P‐N‐S Ligands for Iridium‐Catalyzed Asymmetric Hydrogenation of β‐Alkyl‐β‐Ketoesters

Bao, Deng‐Hui; Wu, Hui‐Ling; Liu, Chao‐Lun; Xie, Jian‐Hua; Zhou, Qi‐Lin. Angew. Chem. Int. Ed. 2015, 54, 8791–8794. DOI: 10.1002/anie.201502860


203. Facile Access to Fluoromethylated Arenes by Nickel‐Catalyzed Cross‐Coupling between Arylboronic Acids and Fluoromethyl Bromide

An, Lun; Xiao, Yu‐Lan; Min, Qiao‐Qiao; Zhang, Xingang. Angew. Chem. Int. Ed. 2015, 54, 9079–9083. DOI: 10.1002/anie.201502882


204. Diastereodivergent Asymmetric 1,4‐Addition of Oxindoles to Nitroolefins by Using Polyfunctional Nickel‐Hydrogen‐Bond‐Azolium Catalysts

Mechler, Melanie; Peters, René. Angew. Chem. Int. Ed. 2015, 54, 10303–10307. DOI: 10.1002/anie.201502930


205. Enantioselective Borylative Dearomatization of Indoles through Copper(I) Catalysis

Kubota, Koji; Hayama, Keiichi; Iwamoto, Hiroaki; Ito, Hajime. Angew. Chem. Int. Ed. 2015, 54, 8809–8813. DOI: 10.1002/anie.201502964


206. Stereoselective Organocatalytic Synthesis of Oxindoles with Adjacent Tetrasubstituted Stereocenters

Engl, Oliver D.; Fritz, Sven P.; Wennemers, Helma. Angew. Chem. Int. Ed. 2015, 54, 8193–8197. DOI: 10.1002/anie.201502976


207. Three‐Component Azidation of Styrene‐Type Double Bonds: Light‐Switchable Behavior of a Copper Photoredox Catalyst

Fumagalli, Gabriele; Rabet, Pauline T. G.; Boyd, Scott; Greaney, Michael F.. Angew. Chem. Int. Ed. 2015, 54, 11481–11484. DOI: 10.1002/anie.201502980


208. Catalytic Asymmetric Synthesis of Phosphine Boronates

Hornillos, Valentín; Vila, Carlos; Otten, Edwin; Feringa, Ben L.. Angew. Chem. Int. Ed. 2015, 54, 7867–7871. DOI: 10.1002/anie.201502987


209. Copper‐Catalyzed Intermolecular Asymmetric Propargylic Dearomatization of Indoles

Shao, Wen; Li, He; Liu, Chuan; Liu, Chen‐Jiang; You, Shu‐Li. Angew. Chem. Int. Ed. 2015, 54, 7684–7687. DOI: 10.1002/anie.201503042


210. Application of a CC Bond‐Forming Conjugate Addition Reaction in Asymmetric Dearomatization of β‐Naphthols

Yang, Dongxu; Wang, Linqing; Kai, Ming; Li, Dan; Yao, Xiaojun; Wang, Rui. Angew. Chem. Int. Ed. 2015, 54, 9523–9527. DOI: 10.1002/anie.201503056


211. Catalytic Enantioselective Reaction of α‐Aminoacetonitriles Using Chiral Bis(imidazoline) Palladium Catalysts

Kondo, Masaru; Nishi, Tomoki; Hatanaka, Tsubasa; Funahashi, Yasuhiro; Nakamura, Shuichi. Angew. Chem. Int. Ed. 2015, 54, 8198–8202. DOI: 10.1002/anie.201503098


212. Rhodium(I)‐Catalyzed Sequential C(sp)C(sp3) and C(sp3)C(sp3) Bond Formation through Migratory Carbene Insertion

Xia, Ying; Feng, Sheng; Liu, Zhen; Zhang, Yan; Wang, Jianbo. Angew. Chem. Int. Ed. 2015, 54, 7891–7894. DOI: 10.1002/anie.201503140


213. Organocatalytic Glycosylation by Using Electron‐Deficient Pyridinium Salts

Das, Somnath; Pekel, Daniel; Neudörfl, Jörg‐M.; Berkessel, Albrecht. Angew. Chem. Int. Ed. 2015, 54, 12479–12483. DOI: 10.1002/anie.201503156


214. Boron‐Catalyzed Regioselective Deoxygenation of Terminal 1,2‐Diols to 2‐Alkanols Enabled by the Strategic Formation of a Cyclic Siloxane Intermediate

Drosos, Nikolaos; Morandi, Bill. Angew. Chem. Int. Ed. 2015, 54, 8814–8818. DOI: 10.1002/anie.201503172


215. Asymmetric Synthesis of Axially Chiral Isoquinolones: Nickel‐Catalyzed Denitrogenative Transannulation

Fang, Zhi‐Jia; Zheng, Sheng‐Cai; Guo, Zhen; Guo, Jing‐Yao; Tan, Bin; Liu, Xin‐Yuan. Angew. Chem. Int. Ed. 2015, 54, 9528–9532. DOI: 10.1002/anie.201503207


216. Visible‐Light Photoredox‐Catalyzed Semipinacol‐Type Rearrangement: Trifluoromethylation/Ring Expansion by a Radical–Polar Mechanism

Sahoo, Basudev; Li, Jun‐Long; Glorius, Frank. Angew. Chem. Int. Ed. 2015, 54, 11577–11580. DOI: 10.1002/anie.201503210


217. Pyridylidene‐Mediated Dihydrogen Activation Coupled with Catalytic Imine Reduction

Auth, Johanna; Padevet, Jaroslav; Mauleón, Pablo; Pfaltz, Andreas. Angew. Chem. Int. Ed. 2015, 54, 9542–9545. DOI: 10.1002/anie.201503233


218. Hydroaminomethylation Beyond Carbonylation: Allene–Imine Reductive Coupling by Ruthenium‐Catalyzed Transfer Hydrogenation

Oda, Susumu; Sam, Brannon; Krische, Michael J.. Angew. Chem. Int. Ed. 2015, 54, 8525–8528. DOI: 10.1002/anie.201503250


219. Nickel‐Catalyzed Alkyl–Alkyl Cross‐Couplings of Fluorinated Secondary Electrophiles: A General Approach to the Synthesis of Compounds having a Perfluoroalkyl Substituent

Liang, Yufan; Fu, Gregory C.. Angew. Chem. Int. Ed. 2015, 54, 9047–9051. DOI: 10.1002/anie.201503297


220. Gold(I)‐Catalyzed Desymmetrization of 1,4‐Dienes by an Enantioselective Tandem Alkoxylation/Claisen Rearrangement

Wu, Hongmiao; Zi, Weiwei; Li, Guigen; Lu, Hongjian; Toste, F. Dean. Angew. Chem. Int. Ed. 2015, 54, 8529–8532. DOI: 10.1002/anie.201503357


221. Organocatalytic Asymmetric 1,6‐Addition/1,4‐Addition Sequence to 2,4‐Dienals for the Synthesis of Chiral Chromans

Poulsen, Pernille H.; Feu, Karla Santos; Paz, Bruno Matos; Jensen, Frank; Jørgensen, Karl Anker. Angew. Chem. Int. Ed. 2015, 54, 8203–8207. DOI: 10.1002/anie.201503370


222. Catalytic Intramolecular Aminofluorination, Oxyfluorination, and Carbofluorination with a Stable and Versatile Hypervalent Fluoroiodine Reagent

Yuan, Weiming; Szabó, Kálmán J.. Angew. Chem. Int. Ed. 2015, 54, 8533–8537. DOI: 10.1002/anie.201503373


223. Gadolinium‐Catalyzed Regio‐ and Enantioselective Aminolysis of Aromatic trans‐2,3‐Epoxy Sulfonamides

Wang, Chuan; Yamamoto, Hisashi. Angew. Chem. Int. Ed. 2015, 54, 8760–8763. DOI: 10.1002/anie.201503391


224. Participation of Alkoxy Groups in Reactions of Acetals: Violation of the Reactivity/Selectivity Principle in a Curtin–Hammett Kinetic Scenario

Garcia, Angie; Sanzone, Jillian R.; Woerpel, K. A.. Angew. Chem. Int. Ed. 2015, 54, 12087–12090. DOI: 10.1002/anie.201503525


225. Organocatalyzed Asymmetric Conjugate Addition of Heteroaryl and Aryl Trifluoroborates: a Synthetic Strategy for Discoipyrrole D

Shih, Jiun‐Le; Nguyen, Thien S.; May, Jeremy A.. Angew. Chem. Int. Ed. 2015, 54, 9931–9935. DOI: 10.1002/anie.201503528


226. Catalytic Stereoinversion of L‐Alanine to Deuterated D‐Alanine

Moozeh, Kimia; So, Soon Mog; Chin, Jik. Angew. Chem. Int. Ed. 2015, 54, 9381–9385. DOI: 10.1002/anie.201503616


227. The Retro‐Hydroformylation Reaction

Kusumoto, Shuhei; Tatsuki, Toshiumi; Nozaki, Kyoko. Angew. Chem. Int. Ed. 2015, 54, 8458–8461. DOI: 10.1002/anie.201503620


228. Highly Robust Palladium(II) α‐Diimine Catalysts for Slow‐Chain‐Walking Polymerization of Ethylene and Copolymerization with Methyl Acrylate

Dai, Shengyu; Sui, Xuelin; Chen, Changle. Angew. Chem. Int. Ed. 2015, 54, 9948–9953. DOI: 10.1002/anie.201503708


229. Bioinduced Room‐Temperature Methanol Reforming

Heim, Leo E.; Thiel, Daniel; Gedig, Christian; Deska, Jan; Prechtl, Martin H. G.. Angew. Chem. Int. Ed. 2015, 54, 10308–10312. DOI: 10.1002/anie.201503737


230. Enantioselective α‐Alkylation of Aldehydes by Photoredox Organocatalysis: Rapid Access to Pharmacophore Fragments from β‐Cyanoaldehydes

Welin, Eric R.; Warkentin, Alexander A.; Conrad, Jay C.; MacMillan, David W. C.. Angew. Chem. Int. Ed. 2015, 54, 9668–9672. DOI: 10.1002/anie.201503789


231. Enantioselective Synthesis of Quaternary Carbon Stereocenters: Addition of 3‐Substituted Oxindoles to Vinyl Sulfone Catalyzed by Pentanidiums

Zong, Lili; Du, Shubo; Chin, Kek Foo; Wang, Chao; Tan, Choon‐Hong. Angew. Chem. Int. Ed. 2015, 54, 9390–9393. DOI: 10.1002/anie.201503844


232. Boron‐Catalyzed N‐Alkylation of Amines using Carboxylic Acids

Fu, Ming‐Chen; Shang, Rui; Cheng, Wan‐Min; Fu, Yao. Angew. Chem. Int. Ed. 2015, 54, 9042–9046. DOI: 10.1002/anie.201503879


233. Copper‐Catalyzed Intramolecular Desymmetric Aryl CO Coupling for the Enantioselective Construction of Chiral Dihydrobenzofurans and Dihydrobenzopyrans

Yang, Wenqiang; Liu, Yangyuan; Zhang, Shasha; Cai, Qian. Angew. Chem. Int. Ed. 2015, 54, 8805–8808. DOI: 10.1002/anie.201503882


234. Cp*RhIII‐Catalyzed Arylation of C(sp3)H Bonds

Wang, Xiaoming; Yu, Da‐Gang; Glorius, Frank. Angew. Chem. Int. Ed. 2015, 54, 10280–10283. DOI: 10.1002/anie.201503888


235. Highly E‐Selective and Enantioselective Michael Addition to Electron‐Deficient Internal Alkynes Under Chiral Iminophosphorane Catalysis

Uraguchi, Daisuke; Yamada, Kohei; Ooi, Takashi. Angew. Chem. Int. Ed. 2015, 54, 9954–9957. DOI: 10.1002/anie.201503928


236. Dialkyl Ether Formation by Nickel‐Catalyzed Cross‐Coupling of Acetals and Aryl Iodides

Arendt, Kevin M.; Doyle, Abigail G.. Angew. Chem. Int. Ed. 2015, 54, 9876–9880. DOI: 10.1002/anie.201503936


237. Disulfonimide‐Catalyzed Asymmetric Reduction of N‐Alkyl Imines

Wakchaure, Vijay N.; Kaib, Philip S. J.; Leutzsch, Markus; List, Benjamin. Angew. Chem. Int. Ed. 2015, 54, 11852–11856. DOI: 10.1002/anie.201504052


238. Effective Formylation of Amines with Carbon Dioxide and Diphenylsilane Catalyzed by Chelating bis(tzNHC) Rhodium Complexes

Nguyen, Thanh V. Q.; Yoo, Woo‐Jin; Kobayashi, Shū. Angew. Chem. Int. Ed. 2015, 54, 9209–9212. DOI: 10.1002/anie.201504072


239. The Cleavage of a CC Bond in Cyclobutylanilines by Visible‐Light Photoredox Catalysis: Development of a [4+2] Annulation Method

Wang, Jiang; Zheng, Nan. Angew. Chem. Int. Ed. 2015, 54, 11424–11427. DOI: 10.1002/anie.201504076


240. 10‐Step Asymmetric Total Synthesis and Stereochemical Elucidation of (+)‐Dragmacidin D

Jackson, Jeffrey J.; Kobayashi, Hiroyuki; Steffens, Sophia D.; Zakarian, Armen. Angew. Chem. Int. Ed. 2015, 54, 9971–9975. DOI: 10.1002/anie.201504113


241. Rhodium(III)‐Catalyzed Allylic C(sp3)–H Activation of Alkenyl Sulfonamides: Unexpected Formation of Azabicycles

Archambeau, Alexis; Rovis, Tomislav. Angew. Chem. Int. Ed. 2015, 54, 13337–13340. DOI: 10.1002/anie.201504150


242. N‐Heterocyclic Olefins as Organocatalysts for Polymerization: Preparation of Well‐Defined Poly(propylene oxide)

Naumann, Stefan; Thomas, Anthony W.; Dove, Andrew P.. Angew. Chem. Int. Ed. 2015, 54, 9550–9554. DOI: 10.1002/anie.201504175


243. Regioselective and 1,2‐cis‐α‐Stereoselective Glycosylation Utilizing Glycosyl‐Acceptor‐Derived Boronic Ester Catalyst

Nakagawa, Akira; Tanaka, Masamichi; Hanamura, Shun; Takahashi, Daisuke; Toshima, Kazunobu. Angew. Chem. Int. Ed. 2015, 54, 10935–10939. DOI: 10.1002/anie.201504182


244. Direct Catalytic Asymmetric Doubly Vinylogous Michael Addition of α,β‐Unsaturated γ‐Butyrolactams to Dienones

Gu, Xiaodong; Guo, Tingting; Dai, Yuanyuan; Franchino, Allegra; Fei, Jie; Zou, Chuncheng; Dixon, Darren J.; Ye, Jinxing. Angew. Chem. Int. Ed. 2015, 54, 10249–10253. DOI: 10.1002/anie.201504276


245. [2+2] Photocycloaddition of Cinnamates in Flow and Development of a Thiourea Catalyst

Telmesani, Reem; Park, Sung H.; Lynch‐Colameta, Tessa; Beeler, Aaron B.. Angew. Chem. Int. Ed. 2015, 54, 11521–11525. DOI: 10.1002/anie.201504454


246. Rhodium(III)‐Catalyzed Activation of C sp 3H Bonds and Subsequent Intermolecular Amidation at Room Temperature

Huang, Xiaolei; Wang, Yan; Lan, Jingbo; You, Jingsong. Angew. Chem. Int. Ed. 2015, 54, 9404–9408. DOI: 10.1002/anie.201504507


247. Cationic Iridium/S‐Me‐BIPAM‐Catalyzed Direct Asymmetric Intermolecular Hydroarylation of Bicycloalkenes

Shirai, Tomohiko; Yamamoto, Yasunori. Angew. Chem. Int. Ed. 2015, 54, 9894–9897. DOI: 10.1002/anie.201504563


248. An Enantioselective Synthesis of Spirobilactams through Copper‐Catalyzed Intramolecular Double N‐Arylation and Phase Separation

Liu, Jianguang; Tian, Yingying; Shi, Jialing; Zhang, Shasha; Cai, Qian. Angew. Chem. Int. Ed. 2015, 54, 10917–10920. DOI: 10.1002/anie.201504589


249. Asymmetric Construction of Spirooxindoles by Organocatalytic Multicomponent Reactions Using Diazooxindoles

Wu, Ming‐Yue; He, Wei‐Wei; Liu, Xin‐Yuan; Tan, Bin. Angew. Chem. Int. Ed. 2015, 54, 9409–9413. DOI: 10.1002/anie.201504640


250. Final‐Stage Site‐Selective Acylation for the Total Syntheses of Multifidosides A–C

Ueda, Yoshihiro; Furuta, Takumi; Kawabata, Takeo. Angew. Chem. Int. Ed. 2015, 54, 11966–11970. DOI: 10.1002/anie.201504729


251. Forming Stereogenic Centers in Acyclic Systems from Alkynes

Vabre, Roxane; Island, Biana; Diehl, Claudia J.; Schreiner, Peter R.; Marek, Ilan. Angew. Chem. Int. Ed. 2015, 54, 9996–9999. DOI: 10.1002/anie.201504756


252. Practical Electrochemical Anodic Oxidation of Polycyclic Lactams for Late Stage Functionalization

Frankowski, Kevin J.; Liu, Ruzhang; Milligan, Gregory L.; Moeller, Kevin D.; Aubé, Jeffrey. Angew. Chem. Int. Ed. 2015, 54, 10555–10558. DOI: 10.1002/anie.201504775


253. Sodium Salts of Anionic Chiral Cobalt(III) Complexes as Catalysts of the Enantioselective Povarov Reaction

Yu, Jie; Jiang, Hua‐Jie; Zhou, Ya; Luo, Shi‐Wei; Gong, Liu‐Zhu. Angew. Chem. Int. Ed. 2015, 54, 11209–11213. DOI: 10.1002/anie.201504790


254. Biomimetic Total Synthesis of (−)‐Penibruguieramine A Using Memory of Chirality and Dynamic Kinetic Resolution

Kim, Jae Hyun; Lee, Seokwoo; Kim, Sanghee. Angew. Chem. Int. Ed. 2015, 54, 10875–10878. DOI: 10.1002/anie.201504954


255. Synergistic Catalysis: Metal/Proton‐Catalyzed Cyclization of Alkynones Toward Bicyclo[3.n.1]alkanones

Zhu, Shifa; Zhang, Qiaohui; Chen, Kai; Jiang, Huanfeng. Angew. Chem. Int. Ed. 2015, 54, 9414–9418. DOI: 10.1002/anie.201504964


256. Controllable Chemoselectivity in Visible‐Light Photoredox Catalysis: Four Diverse Aerobic Radical Cascade Reactions

Liu, Xinfei; Ye, Xinyi; Bureš, Filip; Liu, Hongjun; Jiang, Zhiyong. Angew. Chem. Int. Ed. 2015, 54, 11443–11447. DOI: 10.1002/anie.201505193


257. Enantioselective ortho‐CH Cross‐Coupling of Diarylmethylamines with Organoborons

Laforteza, Brian N.; Chan, Kelvin S. L.; Yu, Jin‐Quan. Angew. Chem. Int. Ed. 2015, 54, 11143–11146. DOI: 10.1002/anie.201505204


258. Benzylic C(sp3)H Perfluoroalkylation of Six‐Membered Heteroaromatic Compounds

Kuninobu, Yoichiro; Nagase, Masahiro; Kanai, Motomu. Angew. Chem. Int. Ed. 2015, 54, 10263–10266. DOI: 10.1002/anie.201505335


259. Pushing the Limits of Neutral Organic Electron Donors: A Tetra(iminophosphorano)‐Substituted Bispyridinylidene

Hanson, Samuel S.; Doni, Eswararao; Traboulsee, Kyle T.; Coulthard, Graeme; Murphy, John A.; Dyker, C. Adam. Angew. Chem. Int. Ed. 2015, 54, 11236–11239. DOI: 10.1002/anie.201505378


260. Photoredox‐Catalyzed Stereoselective Conversion of Alkynes into Tetrasubstituted Trifluoromethylated Alkenes

Tomita, Ren; Koike, Takashi; Akita, Munetaka. Angew. Chem. Int. Ed. 2015, 54, 12923–12927. DOI: 10.1002/anie.201505550


261. Turning Cucurbit[8]uril into a Supramolecular Nanoreactor for Asymmetric Catalysis

Zheng, Lifei; Sonzini, Silvia; Ambarwati, Masyitha; Rosta, Edina; Scherman, Oren A.; Herrmann, Andreas. Angew. Chem. Int. Ed. 2015, 54, 13007–13011. DOI: 10.1002/anie.201505628


262. Catalytic Asymmetric Iodocyclization of N‐Tosyl Alkenamides using Aminoiminophenoxy Copper Carboxylate: A Concise Synthesis of Chiral 8‐Oxa‐6‐Azabicyclo[3.2.1]octanes

Arai, Takayoshi; Watanabe, Ohji; Yabe, Shinnosuke; Yamanaka, Masahiro. Angew. Chem. Int. Ed. 2015, 54, 12767–12771. DOI: 10.1002/anie.201505748


263. Phosphothreonine as a Catalytic Residue in Peptide‐Mediated Asymmetric Transfer Hydrogenations of 8‐Aminoquinolines

Shugrue, Christopher R.; Miller, Scott J.. Angew. Chem. Int. Ed. 2015, 54, 11173–11176. DOI: 10.1002/anie.201505898


264. Chiral γ‐Lactams by Enantioselective Palladium(0)‐Catalyzed Cyclopropane Functionalizations

Pedroni, Julia; Cramer, Nicolai. Angew. Chem. Int. Ed. 2015, 54, 11826–11829. DOI: 10.1002/anie.201505916


265. Organomediated Enantioselective 18F Fluorination for PET Applications

Buckingham, Faye; Kirjavainen, Anna K.; Forsback, Sarita; Krzyczmonik, Anna; Keller, Thomas; Newington, Ian M.; Glaser, Matthias; Luthra, Sajinder K.; Solin, Olof; Gouverneur, Véronique. Angew. Chem. Int. Ed. 2015, 54, 13366–13369. DOI: 10.1002/anie.201506035


266. Mechanism‐Driven Elaboration of an Enantioselective Bromocyclopropanation Reaction of Allylic Alcohols

Taillemaud, Sylvain; Diercxsens, Nicolas; Gagnon, Alexandre; Charette, André B.. Angew. Chem. Int. Ed. 2015, 54, 14108–14112. DOI: 10.1002/anie.201506083


267. Mitsunobu Reactions Catalytic in Phosphine and a Fully Catalytic System

Buonomo, Joseph A.; Aldrich, Courtney C.. Angew. Chem. Int. Ed. 2015, 54, 13041–13044. DOI: 10.1002/anie.201506263


268. Aerobic Asymmetric Dehydrogenative Cross‐Coupling between Two C sp 3H Groups Catalyzed by a Chiral‐at‐Metal Rhodium Complex

Tan, Yuqi; Yuan, Wei; Gong, Lei; Meggers, Eric. Angew. Chem. Int. Ed. 2015, 54, 13045–13048. DOI: 10.1002/anie.201506273


269. Chiral Cyclopentadienyl Iridium(III) Complexes Promote Enantioselective Cycloisomerizations Giving Fused Cyclopropanes

Dieckmann, Michael; Jang, Yun‐Suk; Cramer, Nicolai. Angew. Chem. Int. Ed. 2015, 54, 12149–12152. DOI: 10.1002/anie.201506483


270. Catalytic Asymmetric 1,6‐Conjugate Addition of para‐Quinone Methides: Formation of All‐Carbon Quaternary Stereocenters

Wang, Zhaobin; Wong, Yuk Fai; Sun, Jianwei. Angew. Chem. Int. Ed. 2015, 54, 13711–13714. DOI: 10.1002/anie.201506701


271. Catalytic Nucleophilic Fluorination of Secondary and Tertiary Propargylic Electrophiles with a Copper–N‐Heterocyclic Carbene Complex

Cheng, Li‐Jie; Cordier, Christopher J.. Angew. Chem. Int. Ed. 2015, 54, 13734–13738. DOI: 10.1002/anie.201506882


272. Stereodivergent Dual Catalytic α‐Allylation of Protected α‐Amino‐ and α‐Hydroxyacetaldehydes

Sandmeier, Tobias; Krautwald, Simon; Zipfel, Hannes F.; Carreira, Erick M.. Angew. Chem. Int. Ed. 2015, 54, 14363–14367. DOI: 10.1002/anie.201506933


273. Visible‐Light‐Catalyzed Direct Benzylic C(sp3)–H Amination Reaction by Cross‐Dehydrogenative Coupling

Pandey, Ganesh; Laha, Ramkrishna. Angew. Chem. Int. Ed. 2015, 54, 14875–14879. DOI: 10.1002/anie.201506990


274. A Visible‐Light‐Mediated Radical Smiles Rearrangement and its Application to the Synthesis of a Difluoro‐Substituted Spirocyclic ORL‐1 Antagonist

Douglas, James J.; Albright, Haley; Sevrin, Martin J.; Cole, Kevin P.; Stephenson, Corey R. J.. Angew. Chem. Int. Ed. 2015, 54, 14898–14902. DOI: 10.1002/anie.201507369


275. Visible‐Light‐Mediated Generation of Nitrogen‐Centered Radicals: Metal‐Free Hydroimination and Iminohydroxylation Cyclization Reactions

Davies, Jacob; Booth, Samuel G.; Essafi, Stephanie; Dryfe, Robert A. W.; Leonori, Daniele. Angew. Chem. Int. Ed. 2015, 54, 14017–14021. DOI: 10.1002/anie.201507641


276. Intramolecular Fluorocyclizations of Unsaturated Carboxylic Acids with a Stable Hypervalent Fluoroiodane Reagent

Geary, Gemma C.; Hope, Eric G.; Stuart, Alison M.. Angew. Chem. Int. Ed. 2015, 54, 14911–14914. DOI: 10.1002/anie.201507790


277. CH Oxidation of Ingenanes Enables Potent and Selective Protein Kinase C Isoform Activation

Jin, Yehua; Yeh, Chien‐Hung; Kuttruff, Christian A.; Jørgensen, Lars; Dünstl, Georg; Felding, Jakob; Natarajan, Swaminathan R.; Baran, Phil S.. Angew. Chem. Int. Ed. 2015, 54, 14044–14048. DOI: 10.1002/anie.201507977


278. Gold(I)‐Catalyzed Enantioselective Desymmetrization of 1,3‐Diols through Intramolecular Hydroalkoxylation of Allenes

Zi, Weiwei; Toste, F. Dean. Angew. Chem. Int. Ed. 2015, 54, 14447–14451. DOI: 10.1002/anie.201508331


279. Highly Enantioselective Aza‐Michael Reaction between Alkyl Amines and β‐Trifluoromethyl β‐Aryl Nitroolefins

Wang, Leming; Chen, Jiean; Huang, Yong. Angew. Chem. Int. Ed. 2015, 54, 15414–15418. DOI: 10.1002/anie.201508371


280. Asymmetric Synthesis of Spiroketals with Aminothiourea Catalysts

Yoneda, Naoki; Fukata, Yukihiro; Asano, Keisuke; Matsubara, Seijiro. Angew. Chem. Int. Ed. 2015, 54, 15497–15500. DOI: 10.1002/anie.201508405


281. Tetraalkylammonium Salts as Hydrogen‐Bonding Catalysts

Shirakawa, Seiji; Liu, Shiyao; Kaneko, Shiho; Kumatabara, Yusuke; Fukuda, Airi; Omagari, Yumi; Maruoka, Keiji. Angew. Chem. Int. Ed. 2015, 54, 15767–15770. DOI: 10.1002/anie.201508659


Org. Lett.

282. Highly Effective Configurational Assignment Using Bisthioureas as Chiral Solvating Agents in the Presence of DABCO

Guangling Bian; Hongjun Fan; Huayin Huang; Shiwei Yang; Hua Zong; Ling Song; Genjin Yang. Org. Lett. 2015, 17, 1369–1372. DOI: 10.1021/acs.orglett.5b00030


283. Enantioselective Direct Functionalization of Indoles by Pd/Sulfoxide-Phosphine-Catalyzed N-Allylic Alkylation

Li-Yan Chen; Xiao-Ye Yu; Jia-Rong Chen; Bin Feng; Hong Zhang; Ying-Hua Qi; Wen-Jing Xiao. Org. Lett. 2015, 17, 1381–1384. DOI: 10.1021/acs.orglett.5b00077


284. Highly Efficient Synthesis of Chiral α-CF3 Amines via Rh-Catalyzed Asymmetric Hydrogenation

Jun Jiang; Wenxin Lu; Hui Lv; Xumu Zhang. Org. Lett. 2015, 17, 1154–1156. DOI: 10.1021/acs.orglett.5b00087


285. Copper(II)-Catalyzed Enantioselective Intramolecular Cyclization of N-Alkenylureas

Shaomin Fu; Honghao Yang; Guoqiang Li; Yuanfu Deng; Huanfeng Jiang; Wei Zeng. Org. Lett. 2015, 17, 1018–1021. DOI: 10.1021/acs.orglett.5b00131


286. Pd-Catalyzed Enantioselective Hydroalkoxylation of Alkoxyallenes with Phenol for Construction of Acyclic O,O-Acetals

Liyin Jiang; Tao Jia; Min Wang; Jian Liao; Peng Cao. Org. Lett. 2015, 17, 1070–1073. DOI: 10.1021/acs.orglett.5b00146


287. Catalytic, Asymmetric, Aldol/O-Conjugate Addition Sequence for the Construction of Highly Substituted Furanoids

Michael A. Calter; Alexander Korotkov. Org. Lett. 2015, 17, 1385–1388. DOI: 10.1021/acs.orglett.5b00154


288. Enantioselective Bromocyclization of Allylic Amides Catalyzed by BINAP Derivatives

Yuji Kawato; Akino Kubota; Hiromi Ono; Hiromichi Egami; Yoshitaka Hamashima. Org. Lett. 2015, 17, 1244–1247. DOI: 10.1021/acs.orglett.5b00220


289. Enantioselective Synthesis of Allenylenol Silyl Ethers via Chiral Lithium Amide Mediated Reduction of Ynenoyl Silanes and Their Diels–Alder Reactions

Michiko Sasaki; Yasuhiro Kondo; Ta-ichi Moto-ishi; Masatoshi Kawahata; Kentaro Yamaguchi; Kei Takeda. Org. Lett. 2015, 17, 1280–1283. DOI: 10.1021/acs.orglett.5b00261


290. Enantioselective Synthesis of Functionalized Pyrazoles by NHC-Catalyzed Reaction of Pyrazolones with α,β-Unsaturated Aldehydes

Santhivardhana Reddy Yetra; Santigopal Mondal; Eringathodi Suresh; Akkattu T. Biju. Org. Lett. 2015, 17, 1417–1420. DOI: 10.1021/acs.orglett.5b00293


291. Organocatalytic Enantioselective 1,3-Dipolar Cycloadditions between Seyferth–Gilbert Reagent and Isatylidene Malononitriles: Synthesis of Chiral Spiro-phosphonylpyrazoline-oxindoles

Taiping Du; Fei Du; Yanqiang Ning; Yungui Peng. Org. Lett. 2015, 17, 1308–1311. DOI: 10.1021/acs.orglett.5b00311


292. Highly Enantioselective Catalytic Cross-Dehydrogenative Coupling of N-Carbamoyl Tetrahydroisoquinolines and Terminal Alkynes

Shutao Sun; Chengkun Li; Paul E. Floreancig; Hongxiang Lou; Lei Liu. Org. Lett. 2015, 17, 1684–1687. DOI: 10.1021/acs.orglett.5b00447


293. Counter-Ion-Dependent Alkyne Iminium Ion Cyclization for Divergent Synthesis of N-Fused Indolylidine, Indole, and Indoline Derivatives Promoted by the Lewis/Bronsted Acid

Santosh J. Gharpure; Yogesh G. Shelke; Dasari Praveen Kumar. Org. Lett. 2015, 17, 1926–1929. DOI: 10.1021/acs.orglett.5b00615


294. Expanding the Forefront of Strong Organic Brønsted Acids: Proton-Catalyzed Hydroamination of Unactivated Alkenes and Activation of Au(I) for Alkyne Hydroamination

Roya Mirabdolbaghi; Travis Dudding. Org. Lett. 2015, 17, 1930–1933. DOI: 10.1021/acs.orglett.5b00617


295. Phase-Vanishing Method with Acetylene Evolution and Its Utilization in Several Organic Syntheses

Ryosuke Matake; Yuki Niwa; Hiroshi Matsubara. Org. Lett. 2015, 17, 2354–2357. DOI: 10.1021/acs.orglett.5b00827


296. Alkene Isomerization–Hydroboration Promoted by Phosphine-Ligated Cobalt Catalysts

Margaret L. Scheuermann; Elizabeth J. Johnson; Paul J. Chirik. Org. Lett. 2015, 17, 2716–2719. DOI: 10.1021/acs.orglett.5b01135


297. Hydrogen Bonded Squaramide-Based Foldable Module Induces Both β- and α-Turns in Hairpin Structures of α-Peptides in Water

Luís Martínez; Gabriel Martorell; Ángel Sampedro; Pablo Ballester; Antoni Costa; Carmen Rotger. Org. Lett. 2015, 17, 2980–2983. DOI: 10.1021/acs.orglett.5b01268


298. Homogeneous Gold-Catalyzed Glycosylations in Continuous Flow

Stefan Matthies; D. Tyler McQuade; Peter H. Seeberger. Org. Lett. 2015, 17, 3670–3673. DOI: 10.1021/acs.orglett.5b01584


299. Asymmetric Construction of Spiro[thiopyranoindole-benzoisothiazole] Scaffold via a Formal [3 + 3] Spiroannulation

Xiang Chen; Jun-Qi Zhang; Shao-Jie Yin; Hai-Yan Li; Wei-Qun Zhou; Xing-Wang Wang. Org. Lett. 2015, 17, 4188–4191. DOI: 10.1021/acs.orglett.5b01951


300. Catalytic Enantioselective 1,4-Iodofunctionalizations of Conjugated Dienes

Chandra Bhushan Tripathi; Santanu Mukherjee. Org. Lett. 2015, 17, 4424–4427. DOI: 10.1021/acs.orglett.5b02026


301. Asymmetric Epoxidation of Alkylidenemalononitriles: Key Step for One-Pot Approach to Enantioenriched 3-Substituted Piperazin-2-ones

Sara Meninno; Andreu Vidal-Albalat; Alessandra Lattanzi. Org. Lett. 2015, 17, 4348–4351. DOI: 10.1021/acs.orglett.5b02186


302. Achiral 2-Hydroxy Protecting Group for the Stereocontrolled Synthesis of 1,2-cis-α-Glycosides by Six-Ring Neighboring Group Participation

Govind P. Singh; Andrew J. A. Watson; Antony J. Fairbanks. Org. Lett. 2015, 17, 4376–4379. DOI: 10.1021/acs.orglett.5b02226


303. Redox-Triggered α-C–H Functionalization of Pyrrolidines: Synthesis of Unsymmetrically 2,5-Disubstituted Pyrrolidines

Yong-Feng Cheng; Hao-Jie Rong; Cheng-Bo Yi; Jun-Jun Yao; Jin Qu. Org. Lett. 2015, 17, 4758–4761. DOI: 10.1021/acs.orglett.5b02298


304. Highly Regio-, Diastereo-, and Enantioselective Mannich Reaction of Allylic Ketones and Cyclic Ketimines: Access to Chiral Benzosultam

Baokun Qiao; Yin-Jun Huang; Jing Nie; Jun-An Ma. Org. Lett. 2015, 17, 4608–4611. DOI: 10.1021/acs.orglett.5b02351


305. Syn-Selective Synthesis of β-Branched α-Amino Acids by Alkylation of Glycine-Derived Imines with Secondary Sulfonates

Sha Lou; Grace M. McKenna; Steven A. Tymonko; Antonio Ramirez; Tamas Benkovics; David A. Conlon; Francisco González-Bobes. Org. Lett. 2015, 17, 5000–5003. DOI: 10.1021/acs.orglett.5b02448


306. General Homologation Strategy for Synthesis of l-glycero- and d-glycero-Heptopyranoses

Shaheen K. Mulani; Kuang-Chun Cheng; Kwok-Kong T. Mong. Org. Lett. 2015, 17, 5536–5539. DOI: 10.1021/acs.orglett.5b02620


307. Photoinduced C–S Bond Cleavage of Thioglycosides and Glycosylation

Run-Ze Mao; Fan Guo; De-Cai Xiong; Qin Li; Jinyou Duan; Xin-Shan Ye. Org. Lett. 2015, 17, 5606–5609. DOI: 10.1021/acs.orglett.5b02823


308. Diastereoselective Synthesis of α-Quaternary Aziridine-2-carboxylates via Aza-Corey–Chaykovsky Aziridination of N-tert-Butanesulfinyl Ketimino Esters

Maurice A. Marsini; Jonathan T. Reeves; Jean-Nicolas Desrosiers; Melissa A. Herbage; Jolaine Savoie; Zhibin Li; Keith R. Fandrick; C. Avery Sader; Bryan McKibben; Donghong A. Gao; Jianwen Cui; Nina C. Gonnella; Heewon Lee; Xudong Wei; Frank Roschangar; Bruce Z. Lu; Chris H. Senanayake. Org. Lett. 2015, 17, 5614–5617. DOI: 10.1021/acs.orglett.5b02838


309. Chiral Pyridoxal-Catalyzed Asymmetric Biomimetic Transamination of α-Keto Acids

Limin Shi; Chuangan Tao; Qin Yang; Yong Ethan Liu; Jing Chen; Jianfeng Chen; Jiaxin Tian; Feng Liu; Bo Li; Yongling Du; Baoguo Zhao. Org. Lett. 2015, 17, 5784–5787. DOI: 10.1021/acs.orglett.5b02895


310. Catalytic Aldol–Cyclization Cascade of 3-Isothiocyanato Oxindoles with α-Ketophosphonates for the Enantioselective Synthesis of β-Amino-α-hydroxyphosphonates

Satavisha Kayal; Santanu Mukherjee. Org. Lett. 2015, 17, 5508–5511. DOI: 10.1021/acs.orglett.5b02929


311. Enantioselective Cyano-Alkoxycarbonylation of α-Oxoesters Promoted by Brønsted Acid–Lewis Base Cooperative Catalysts

Kazuaki Ishihara; Yoshihiro Ogura. Org. Lett. 2015, 17, 6070–6073. DOI: 10.1021/acs.orglett.5b03093


312. Aryl(trifluoroethyl)iodonium Triflimide and Nitrile Solvent Systems: A Combination for the Stereoselective Synthesis of Armed 1,2-trans-β-Glycosides at Noncryogenic Temperatures

An-Hsiang Adam Chu; Andrei Minciunescu; Clay S. Bennett. Org. Lett. 2015, 17, 6262–6265. DOI: 10.1021/acs.orglett.5b03282


J. Am. Chem. Soc.

313. New Powerful and Oxidatively Rugged Dinuclear Ru Water Oxidation Catalyst: Control of Mechanistic Pathways by Tailored Ligand Design

Sven Neudeck; Somnath Maji; Isidoro López; Steffen Meyer; Franc Meyer; Antoni Llobet. J. Am. Chem. Soc. 2014, 136, 24–27. DOI: 10.1021/ja409974b


314. Organocatalytic Enantio- and Diastereoselective Synthesis of 1,2-Dihydronaphthalenes from Isobenzopyrylium Ions

Hui Qian; Wanxiang Zhao; Zhaobin Wang; Jianwei Sun. J. Am. Chem. Soc. 2015, 137, 560–563. DOI: 10.1021/ja509824j


315. Highly Enantioselective Synthesis of 3,4-Dihydropyrans through a Phosphine-Catalyzed [4+2] Annulation of Allenones and β,γ-Unsaturated α-Keto Esters

Weijun Yao; Xiaowei Dou; Yixin Lu. J. Am. Chem. Soc. 2015, 137, 54–57. DOI: 10.1021/ja5109358


316. Catalytic Asymmetric Dearomatizing Redox Cross Coupling of Ketones with Aryl Hydrazines Giving 1,4-Diketones

Shenlin Huang; Lisa Kötzner; Chandra Kanta De; Benjamin List. J. Am. Chem. Soc. 2015, 137, 3446–3449. DOI: 10.1021/ja511200j


317. Tandem Amine and Ruthenium-Catalyzed Hydrogenation of CO2 to Methanol

Nomaan M. Rezayee; Chelsea A. Huff; Melanie S. Sanford. J. Am. Chem. Soc. 2015, 137, 1028–1031. DOI: 10.1021/ja511329m


318. Iridium-Catalyzed Silylation of Aryl C–H Bonds

Chen Cheng; John F. Hartwig. J. Am. Chem. Soc. 2015, 137, 592–595. DOI: 10.1021/ja511352u


319. N-Heterocyclic Carbene-Catalyzed Radical Reactions for Highly Enantioselective β-Hydroxylation of Enals

Yuexia Zhang; Yu Du; Zhijian Huang; Jianfeng Xu; Xingxing Wu; Yuhuang Wang; Ming Wang; Song Yang; Richard D. Webster; Yonggui Robin Chi. J. Am. Chem. Soc. 2015, 137, 2416–2419. DOI: 10.1021/ja511371a


320. Synthesis of Highly Functionalized Tri- and Tetrasubstituted Alkenes via Pd-Catalyzed 1,2-Hydrovinylation of Terminal 1,3-Dienes

Vaneet Saini; Mark O’Dair; Matthew S. Sigman. J. Am. Chem. Soc. 2015, 137, 608–611. DOI: 10.1021/ja511640g


321. Organocatalytic Enantioselective Formal C(sp2)–H Alkylation

Madhu Sudan Manna; Santanu Mukherjee. J. Am. Chem. Soc. 2015, 137, 130–133. DOI: 10.1021/ja5117556


322. Modeling TauD-J: A High-Spin Nonheme Oxoiron(IV) Complex with High Reactivity toward C–H Bonds

Achintesh N. Biswas; Mayank Puri; Katlyn K. Meier; Williamson N. Oloo; Gregory T. Rohde; Emile L. Bominaar; Eckard Münck; Lawrence Que. J. Am. Chem. Soc. 2015, 137, 2428–2431. DOI: 10.1021/ja511757j


323. Fe–P: A New Class of Electroactive Catalyst for Oxygen Reduction Reaction

Kiran Pal Singh; Eun Jin Bae; Jong-Sung Yu. J. Am. Chem. Soc. 2015, 137, 3165–3168. DOI: 10.1021/ja511759u


324. A Phosphetane Catalyzes Deoxygenative Condensation of α-Keto Esters and Carboxylic Acids via PIII/PV═O Redox Cycling

Wei Zhao; Patrick K. Yan; Alexander T. Radosevich. J. Am. Chem. Soc. 2015, 137, 616–619. DOI: 10.1021/ja511889y


325. Ruthenium-Catalyzed Alkene–Alkyne Coupling of Disubstituted Olefins: Application to the Stereoselective Synthesis of Trisubstituted Enecarbamates

Barry M. Trost; James J. Cregg. J. Am. Chem. Soc. 2015, 137, 620–623. DOI: 10.1021/ja511911b


326. Merging Photoredox and Nickel Catalysis: Decarboxylative Cross-Coupling of Carboxylic Acids with Vinyl Halides

Adam Noble; Stefan J. McCarver; David W. C. MacMillan. J. Am. Chem. Soc. 2015, 137, 624–627. DOI: 10.1021/ja511913h


327. Alkyne Hydroacylation: Switching Regioselectivity by Tandem Ruthenium Catalysis

Qing-An Chen; Faben A. Cruz; Vy M. Dong. J. Am. Chem. Soc. 2015, 137, 3157–3160. DOI: 10.1021/ja512015w


328. Kinetic Resolution of Racemic Amino Alcohols through Intermolecular Acetalization Catalyzed by a Chiral Brønsted Acid

Takuto Yamanaka; Azusa Kondoh; Masahiro Terada. J. Am. Chem. Soc. 2015, 137, 1048–1051. DOI: 10.1021/ja512238n


329. Copper-Catalyzed Hydroalkylation of Terminal Alkynes

Mycah R. Uehling; Alison M. Suess; Gojko Lalic. J. Am. Chem. Soc. 2015, 137, 1424–1427. DOI: 10.1021/ja5124368


330. Atom-Economical Transformation of Diaryliodonium Salts: Tandem C–H and N–H Arylation of Indoles

Sachin G. Modha; Michael F. Greaney. J. Am. Chem. Soc. 2015, 137, 1416–1419. DOI: 10.1021/ja5124754


331. Resolution of Diols via Catalytic Asymmetric Acetalization

Ji Hye Kim; Ilija Čorić; Chiara Palumbo; Benjamin List. J. Am. Chem. Soc. 2015, 137, 1778–1781. DOI: 10.1021/ja512481d


332. C–P Bond-Forming Reactions via C–O/P–H Cross-Coupling Catalyzed by Nickel

Jia Yang; Tieqiao Chen; Li-Biao Han. J. Am. Chem. Soc. 2015, 137, 1782–1785. DOI: 10.1021/ja512498u


333. Coupling of Propylene Oxide and Lactide at a Porphyrin Chromium(III) Center

Vagulejan Balasanthiran; Chandrani Chatterjee; Malcolm H. Chisholm; Nicole D. Harrold; T. V. RajanBabu; Grant A. Warren. J. Am. Chem. Soc. 2015, 137, 1786–1789. DOI: 10.1021/ja512554t


334. C–H Activation/Functionalization Catalyzed by Simple, Well-Defined Low-Valent Cobalt Complexes

Brendan J. Fallon; Etienne Derat; Muriel Amatore; Corinne Aubert; Fabrice Chemla; Franck Ferreira; Alejandro Perez-Luna; Marc Petit. J. Am. Chem. Soc. 2015, 137, 2448–2451. DOI: 10.1021/ja512728f


335. Enantioselective Conjugate Additions of α-Amino Radicals via Cooperative Photoredox and Lewis Acid Catalysis

Laura Ruiz Espelt; Iain S. McPherson; Eric M. Wiensch; Tehshik P. Yoon. J. Am. Chem. Soc. 2015, 137, 2452–2455. DOI: 10.1021/ja512746q


336. Palladium-Catalyzed Aerobic Oxidative Dehydrogenation of Cyclohexenes to Substituted Arene Derivatives

Andrei V. Iosub; Shannon S. Stahl. J. Am. Chem. Soc. 2015, 137, 3454–3457. DOI: 10.1021/ja512770u


337. Single-Electron Transmetalation: An Enabling Technology for Secondary Alkylboron Cross-Coupling

David N. Primer; Idris Karakaya; John C. Tellis; Gary A. Molander. J. Am. Chem. Soc. 2015, 137, 2195–2198. DOI: 10.1021/ja512946e


338. Iron Achieves Noble Metal Reactivity and Selectivity: Highly Reactive and Enantioselective Iron Complexes as Catalysts in the Hydrosilylation of Ketones

Tim Bleith; Hubert Wadepohl; Lutz H. Gade. J. Am. Chem. Soc. 2015, 137, 2456–2459. DOI: 10.1021/ja512986m


339. Ruthenium-Catalyzed C–C Coupling of Amino Alcohols with Dienes via Transfer Hydrogenation: Redox-Triggered Imine Addition and Related Hydroaminoalkylations

Te-Yu Chen; Ryosuke Tsutsumi; T. Patrick Montgomery; Ivan Volchkov; Michael J. Krische. J. Am. Chem. Soc. 2015, 137, 1798–1801. DOI: 10.1021/ja5130258


340. Palladium-Catalyzed Enantioselective Heck Alkenylation of Acyclic Alkenols Using a Redox-Relay Strategy

Harshkumar H. Patel; Matthew S. Sigman. J. Am. Chem. Soc. 2015, 137, 3462–3465. DOI: 10.1021/ja5130836


341. Highly Selective Pd-Catalyzed Intermolecular Fluorosulfonylation of Styrenes

Zheliang Yuan; Hao-Yang Wang; Xin Mu; Pinhong Chen; Yin-Long Guo; Guosheng Liu. J. Am. Chem. Soc. 2015, 137, 2468–2471. DOI: 10.1021/ja5131676


342. Synthesis of Alternating trans-AB Copolymers through Ring-Opening Metathesis Polymerization Initiated by Molybdenum Alkylidenes

Hyangsoo Jeong; Jeremy M. John; Richard R. Schrock; Amir H. Hoveyda. J. Am. Chem. Soc. 2015, 137, 2239–2242. DOI: 10.1021/jacs.5b00221


343. Direct Asymmetric Amination of α-Branched Cyclic Ketones Catalyzed by a Chiral Phosphoric Acid

Xiaoyu Yang; F. Dean Toste. J. Am. Chem. Soc. 2015, 137, 3205–3208. DOI: 10.1021/jacs.5b00229


344. Dual Role of Rh(III) Catalyst Enables Regioselective Halogenation of (Electron-Rich) Heterocycles

Nils Schröder; Fabian Lied; Frank Glorius. J. Am. Chem. Soc. 2015, 137, 1448–1451. DOI: 10.1021/jacs.5b00283


345. Enantioselective 1,1-Arylborylation of Alkenes: Merging Chiral Anion Phase Transfer with Pd Catalysis

Hosea M. Nelson; Brett D. Williams; Javier Miró; F. Dean Toste. J. Am. Chem. Soc. 2015, 137, 3213–3216. DOI: 10.1021/jacs.5b00344


346. Diastereoselective Carbonyl Allylation with Simple Olefins Enabled by Palladium Complex-Catalyzed C–H Oxidative Borylation

Zhong-Lin Tao; Xing-Han Li; Zhi-Yong Han; Liu-Zhu Gong. J. Am. Chem. Soc. 2015, 137, 4054–4057. DOI: 10.1021/jacs.5b00507


347. Organocatalytic Diboration Involving “Reductive Addition” of a Boron–Boron σ-Bond to 4,4′-Bipyridine

Toshimichi Ohmura; Yohei Morimasa; Michinori Suginome. J. Am. Chem. Soc. 2015, 137, 2852–2855. DOI: 10.1021/jacs.5b00546


348. Catalytic Enantioselective Allenoate–Alkene [2 + 2] Cycloadditions

Michael L. Conner; Yao Xu; M. Kevin Brown. J. Am. Chem. Soc. 2015, 137, 3482–3485. DOI: 10.1021/jacs.5b00563


349. Gold(I)-Catalyzed Dearomative Rautenstrauch Rearrangement: Enantioselective Access to Cyclopenta[b]indoles

Weiwei Zi; Hongmiao Wu; F. Dean Toste. J. Am. Chem. Soc. 2015, 137, 3225–3228. DOI: 10.1021/jacs.5b00613


350. Palladium-Catalyzed Intermolecular Aminocarbonylation of Alkenes: Efficient Access of β-Amino Acid Derivatives

Jiashun Cheng; Xiaoxu Qi; Ming Li; Pinhong Chen; Guosheng Liu. J. Am. Chem. Soc. 2015, 137, 2480–2483. DOI: 10.1021/jacs.5b00719


351. Enantioselective Ruthenium-Catalyzed Carbonyl Allylation via Alkyne–Alcohol C–C Bond-Forming Transfer Hydrogenation: Allene Hydrometalation vs Oxidative Coupling

Tao Liang; Khoa D. Nguyen; Wandi Zhang; Michael J. Krische. J. Am. Chem. Soc. 2015, 137, 3161–3164. DOI: 10.1021/jacs.5b00747


352. Enantioselective Synthesis of 1,2-Dihydronaphthalene-1-carbaldehydes by Addition of Boronates to Isochromene Acetals Catalyzed by Tartaric Acid

Yi Luan; Keith S. Barbato; Philip N. Moquist; Tomohiro Kodama; Scott E. Schaus. J. Am. Chem. Soc. 2015, 137, 3233–3236. DOI: 10.1021/jacs.5b00757


353. Rhodium(I)-Catalyzed Asymmetric Carbene Insertion into B–H Bonds: Highly Enantioselective Access to Functionalized Organoboranes

Diao Chen; Xu Zhang; Wei-Yi Qi; Bin Xu; Ming-Hua Xu. J. Am. Chem. Soc. 2015, 137, 5268–5271. DOI: 10.1021/jacs.5b00892


354. Iron-Catalyzed C–H Borylation of Arenes

Thomas Dombray; C. Gunnar Werncke; Shi Jiang; Mary Grellier; Laure Vendier; Sébastien Bontemps; Jean-Baptiste Sortais; Sylviane Sabo-Etienne; Christophe Darcel. J. Am. Chem. Soc. 2015, 137, 4062–4065. DOI: 10.1021/jacs.5b00895


355. Cobalt Catalyzed Z-Selective Hydroboration of Terminal Alkynes and Elucidation of the Origin of Selectivity

Jennifer V. Obligacion; Jamie M. Neely; Aliza N. Yazdani; Iraklis Pappas; Paul J. Chirik. J. Am. Chem. Soc. 2015, 137, 5855–5858. DOI: 10.1021/jacs.5b00936


356. Silver-Catalyzed Ring-Opening Strategy for the Synthesis of β- and γ-Fluorinated Ketones

Huijun Zhao; Xuefeng Fan; Jiajia Yu; Chen Zhu. J. Am. Chem. Soc. 2015, 137, 3490–3493. DOI: 10.1021/jacs.5b00939


357. Nickel-Catalyzed Regio- and Enantioselective Aminolysis of 3,4-Epoxy Alcohols

Chuan Wang; Hisashi Yamamoto. J. Am. Chem. Soc. 2015, 137, 4308–4311. DOI: 10.1021/jacs.5b01005


358. Modular C–H Functionalization Cascade of Aryl Iodides

Hang Shi; David J. Babinski; Tobias Ritter. J. Am. Chem. Soc. 2015, 137, 3775–3778. DOI: 10.1021/jacs.5b01082


359. Phosphine-Catalyzed Highly Enantioselective [3 + 3] Cycloaddition of Morita–Baylis–Hillman Carbonates with C,N-Cyclic Azomethine Imines

Lei Zhang; Honglei Liu; Guanyu Qiao; Zhanfeng Hou; Yang Liu; Yumei Xiao; Hongchao Guo. J. Am. Chem. Soc. 2015, 137, 4316–4319. DOI: 10.1021/jacs.5b01138


360. Catalytic Chemo-, Regio-, and Enantioselective Bromochlorination of Allylic Alcohols

Dennis X. Hu; Frederick J. Seidl; Cyril Bucher; Noah Z. Burns. J. Am. Chem. Soc. 2015, 137, 3795–3798. DOI: 10.1021/jacs.5b01384


361. Enantioselective Organocatalytic Alkylation of Aldehydes and Enals Driven by the Direct Photoexcitation of Enamines

Mattia Silvi; Elena Arceo; Igor D. Jurberg; Carlo Cassani; Paolo Melchiorre. J. Am. Chem. Soc. 2015, 137, 6120–6123. DOI: 10.1021/jacs.5b01662


362. Enantioselective Cross-Coupling of meso-Epoxides with Aryl Halides

Yang Zhao; Daniel J. Weix. J. Am. Chem. Soc. 2015, 137, 3237–3240. DOI: 10.1021/jacs.5b01909


363. Visible Light-Driven Water Oxidation Promoted by Host–Guest Interaction between Photosensitizer and Catalyst with A High Quantum Efficiency

Hua Li; Fei Li; Biaobiao Zhang; Xu Zhou; Fengshou Yu; Licheng Sun. J. Am. Chem. Soc. 2015, 137, 4332–4335. DOI: 10.1021/jacs.5b01924


364. Catalytic Asymmetric Direct-Type 1,4-Addition Reactions of Simple Amides

Hirotsugu Suzuki; Io Sato; Yasuhiro Yamashita; Shu̅ Kobayashi. J. Am. Chem. Soc. 2015, 137, 4336–4339. DOI: 10.1021/jacs.5b01943


365. Use of a New Spirophosphine To Achieve Catalytic Enantioselective [4 + 1] Annulations of Amines with Allenes To Generate Dihydropyrroles

Søren Kramer; Gregory C. Fu. J. Am. Chem. Soc. 2015, 137, 3803–3806. DOI: 10.1021/jacs.5b01944


366. Formaldehyde N,N-Dialkylhydrazones as Neutral Formyl Anion Equivalents in Iridium-Catalyzed Asymmetric Allylic Substitution

Simon Breitler; Erick M. Carreira. J. Am. Chem. Soc. 2015, 137, 5296–5299. DOI: 10.1021/jacs.5b01951


367. Dynamic Kinetic Asymmetric Amination of Alcohols: From A Mixture of Four Isomers to Diastereo- and Enantiopure α-Branched Amines

Zi-Qiang Rong; Yao Zhang; Raymond Hong Bing Chua; Hui-Jie Pan; Yu Zhao. J. Am. Chem. Soc. 2015, 137, 4944–4947. DOI: 10.1021/jacs.5b02212


368. Palladium-Catalyzed α,β-Dehydrogenation of Esters and Nitriles

Yifeng Chen; Justin P. Romaire; Timothy R. Newhouse. J. Am. Chem. Soc. 2015, 137, 5875–5878. DOI: 10.1021/jacs.5b02243


369. Decarboxylative Fluorination of Aliphatic Carboxylic Acids via Photoredox Catalysis

Sandrine Ventre; Filip R. Petronijevic; David W. C. MacMillan. J. Am. Chem. Soc. 2015, 137, 5654–5657. DOI: 10.1021/jacs.5b02244


370. Electron-Deficient Olefin Ligands Enable Generation of Quaternary Carbons by Ni-Catalyzed Cross-Coupling

Chung-Yang (Dennis) Huang; Abigail G. Doyle. J. Am. Chem. Soc. 2015, 137, 5638–5641. DOI: 10.1021/jacs.5b02503


371. Simple Amine-Directed Meta-Selective C–H Arylation via Pd/Norbornene Catalysis

Zhe Dong; Jianchun Wang; Guangbin Dong. J. Am. Chem. Soc. 2015, 137, 5887–5890. DOI: 10.1021/jacs.5b02809


372. Rhodium-Catalyzed Enantioselective Silylation of Arene C–H Bonds: Desymmetrization of Diarylmethanols

Taegyo Lee; Tyler W. Wilson; Robert Berg; Per Ryberg; John F. Hartwig. J. Am. Chem. Soc. 2015, 137, 6742–6745. DOI: 10.1021/jacs.5b03091


373. Photo-organocatalytic Enantioselective Perfluoroalkylation of β-Ketoesters

Łukasz Woźniak; John J. Murphy; Paolo Melchiorre. J. Am. Chem. Soc. 2015, 137, 5678–5681. DOI: 10.1021/jacs.5b03243


374. Bond-Weakening Catalysis: Conjugate Aminations Enabled by the Soft Homolysis of Strong N–H Bonds

Kyle T. Tarantino; David C. Miller; Ted A. Callon; Robert R. Knowles. J. Am. Chem. Soc. 2015, 137, 6440–6443. DOI: 10.1021/jacs.5b03428


375. Enantio- and Diastereoselective Synthesis of 1,2-Hydroxyboronates through Cu-Catalyzed Additions of Alkylboronates to Aldehydes

Matthew V. Joannou; Brandon S. Moyer; Simon J. Meek. J. Am. Chem. Soc. 2015, 137, 6176–6179. DOI: 10.1021/jacs.5b03477


376. Stereospecific Intramolecular Reductive Cross-Electrophile Coupling Reactions for Cyclopropane Synthesis

Emily J. Tollefson; Lucas W. Erickson; Elizabeth R. Jarvo. J. Am. Chem. Soc. 2015, 137, 9760–9763. DOI: 10.1021/jacs.5b03870


377. Chemoselective Boron-Catalyzed Nucleophilic Activation of Carboxylic Acids for Mannich-Type Reactions

Yuya Morita; Tomohiro Yamamoto; Hideoki Nagai; Yohei Shimizu; Motomu Kanai. J. Am. Chem. Soc. 2015, 137, 7075–7078. DOI: 10.1021/jacs.5b04175


378. Silica-Supported Cationic Gold(I) Complexes as Heterogeneous Catalysts for Regio- and Enantioselective Lactonization Reactions

Xing-Zhong Shu; Son C. Nguyen; Ying He; Fadekemi Oba; Qiao Zhang; Christian Canlas; Gabor A. Somorjai; A. Paul Alivisatos; F. Dean Toste. J. Am. Chem. Soc. 2015, 137, 7083–7086. DOI: 10.1021/jacs.5b04294


379. A Nucleophilic Strategy for Enantioselective Intermolecular α-Amination: Access to Enantioenriched α-Arylamino Ketones

Dillon H. Miles; Joan Guasch; F. Dean Toste. J. Am. Chem. Soc. 2015, 137, 7632–7635. DOI: 10.1021/jacs.5b04518


380. Catalytic Asymmetric Arylation of α-Aryl-α-diazoacetates with Aniline Derivatives

Bin Xu; Mao-Lin Li; Xiao-Dong Zuo; Shou-Fei Zhu; Qi-Lin Zhou. J. Am. Chem. Soc. 2015, 137, 8700–8703. DOI: 10.1021/jacs.5b05086


381. Hydromethylation of Unactivated Olefins

Hai T. Dao; Chao Li; Quentin Michaudel; Brad D. Maxwell; Phil S. Baran. J. Am. Chem. Soc. 2015, 137, 8046–8049. DOI: 10.1021/jacs.5b05144


382. Catalytic Enantioselective Peroxidation of α,β-Unsaturated Aldehydes for the Asymmetric Synthesis of Biologically Important Chiral Endoperoxides

Lin Hu; Xiaojie Lu; Li Deng. J. Am. Chem. Soc. 2015, 137, 8400–8403. DOI: 10.1021/jacs.5b05345


383. Highly Regioselective Indoline Synthesis under Nickel/Photoredox Dual Catalysis

Sarah Z. Tasker; Timothy F. Jamison. J. Am. Chem. Soc. 2015, 137, 9531–9534. DOI: 10.1021/jacs.5b05597


384. Intramolecular Tsuji–Trost-type Allylation of Carboxylic Acids: Asymmetric Synthesis of Highly π-Allyl Donative Lactones

Yusuke Suzuki; Tomoaki Seki; Shinji Tanaka; Masato Kitamura. J. Am. Chem. Soc. 2015, 137, 9539–9542. DOI: 10.1021/jacs.5b05786


385. Synthesis of Enantioenriched Alkylfluorides by the Fluorination of Boronate Complexes

Christopher Sandford; Ramesh Rasappan; Varinder K. Aggarwal. J. Am. Chem. Soc. 2015, 137, 10100–10103. DOI: 10.1021/jacs.5b05848


386. Enantioselective Synthesis of Hemiaminals via Pd-Catalyzed C–N Coupling with Chiral Bisphosphine Mono-oxides

Hongming Li; Kevin M. Belyk; Jingjun Yin; Qinghao Chen; Alan Hyde; Yining Ji; Steven Oliver; Matthew T. Tudge; Louis-Charles Campeau; Kevin R. Campos. J. Am. Chem. Soc. 2015, 137, 13728–13731. DOI: 10.1021/jacs.5b05934


387. Enantioselective, Catalytic Trichloromethylation through Visible-Light-Activated Photoredox Catalysis with a Chiral Iridium Complex

Haohua Huo; Chuanyong Wang; Klaus Harms; Eric Meggers. J. Am. Chem. Soc. 2015, 137, 9551–9554. DOI: 10.1021/jacs.5b06010


388. Nitro-Assisted Brønsted Acid Catalysis: Application to a Challenging Catalytic Azidation

Marian Dryzhakov; Malik Hellal; Eléna Wolf; Florian C. Falk; Joseph Moran. J. Am. Chem. Soc. 2015, 137, 9555–9558. DOI: 10.1021/jacs.5b06055


389. Iron-Catalyzed Reduction of CO2 into Methylene: Formation of C–N, C–O, and C–C Bonds

Guanghua Jin; C. Gunnar Werncke; Yannick Escudié; Sylviane Sabo-Etienne; Sébastien Bontemps. J. Am. Chem. Soc. 2015, 137, 9563–9566. DOI: 10.1021/jacs.5b06077


390. PyFluor: A Low-Cost, Stable, and Selective Deoxyfluorination Reagent

Matthew K. Nielsen; Christian R. Ugaz; Wenping Li; Abigail G. Doyle. J. Am. Chem. Soc. 2015, 137, 9571–9574. DOI: 10.1021/jacs.5b06307


391. Supramolecular Ga4L612– Cage Photosensitizes 1,3-Rearrangement of Encapsulated Guest via Photoinduced Electron Transfer

Derek M. Dalton; Scott R. Ellis; Eva M. Nichols; Richard A. Mathies; F. Dean Toste; Robert G. Bergman; Kenneth N. Raymond. J. Am. Chem. Soc. 2015, 137, 10128–10131. DOI: 10.1021/jacs.5b06317


392. Oxidatively Initiated NHC-Catalyzed Enantioselective Synthesis of 3,4-Disubstituted Cyclopentanones from Enals

Nicholas A. White; Tomislav Rovis. J. Am. Chem. Soc. 2015, 137, 10112–10115. DOI: 10.1021/jacs.5b06390


393. Catalytic Asymmetric Cascade Vinylogous Mukaiyama 1,6-Michael/Michael Addition of 2-Silyloxyfurans with Azoalkenes: Direct Approach to Fused Butyrolactones

Jun Li; Rong Huang; Yi-Kang Xing; Guofu Qiu; Hai-Yan Tao; Chun-Jiang Wang. J. Am. Chem. Soc. 2015, 137, 10124–10127. DOI: 10.1021/jacs.5b06509


394. Asymmetric Fluorolactonization with a Bifunctional Hydroxyl Carboxylate Catalyst

Hiromichi Egami; Junshi Asada; Kentaro Sato; Daisuke Hashizume; Yuji Kawato; Yoshitaka Hamashima. J. Am. Chem. Soc. 2015, 137, 10132–10135. DOI: 10.1021/jacs.5b06546


395. Aminoboration: Addition of B–N σ Bonds across C–C π Bonds

Eugene Chong; Suzanne A. Blum. J. Am. Chem. Soc. 2015, 137, 10144–10147. DOI: 10.1021/jacs.5b06678


396. α-Arylation of Saturated Azacycles and N-Methylamines via Palladium(II)-Catalyzed C(sp3)–H Coupling

Jillian E. Spangler; Yoshihisa Kobayashi; Pritha Verma; Dong-Hui Wang; Jin-Quan Yu. J. Am. Chem. Soc. 2015, 137, 11876–11879. DOI: 10.1021/jacs.5b06740


397. Remote para-C–H Functionalization of Arenes by a D-Shaped Biphenyl Template-Based Assembly

Sukdev Bag; Tuhin Patra; Atanu Modak; Arghya Deb; Soham Maity; Uttam Dutta; Aniruddha Dey; Rajesh Kancherla; Arun Maji; Avijit Hazra; Milan Bera; Debabrata Maiti. J. Am. Chem. Soc. 2015, 137, 11888–11891. DOI: 10.1021/jacs.5b06793


398. A Bio-Inspired, Catalytic EZ Isomerization of Activated Olefins

Jan B. Metternich; Ryan Gilmour. J. Am. Chem. Soc. 2015, 137, 11254–11257. DOI: 10.1021/jacs.5b07136


399. Asymmetric Pd-Catalyzed Alkene Carboamination Reactions for the Synthesis of 2-Aminoindane Derivatives

Derick R. White; Johnathon T. Hutt; John P. Wolfe. J. Am. Chem. Soc. 2015, 137, 11246–11249. DOI: 10.1021/jacs.5b07203


400. Asymmetric Anion-π Catalysis: Enamine Addition to Nitroolefins on π-Acidic Surfaces

Yingjie Zhao; Yoann Cotelle; Alyssa-Jennifer Avestro; Naomi Sakai; Stefan Matile. J. Am. Chem. Soc. 2015, 137, 11582–11585. DOI: 10.1021/jacs.5b07382


401. Cyclic Ether Synthesis via Palladium-Catalyzed Directed Dehydrogenative Annulation at Unactivated Terminal Positions

Samuel J. Thompson; Danny Q. Thach; Guangbin Dong. J. Am. Chem. Soc. 2015, 137, 11586–11589. DOI: 10.1021/jacs.5b07384


402. Iridium-Catalyzed Enantioselective Fluorination of Racemic, Secondary Allylic Trichloroacetimidates

Qi Zhang; David P. Stockdale; Jason C. Mixdorf; Joseph J. Topczewski; Hien M. Nguyen. J. Am. Chem. Soc. 2015, 137, 11912–11915. DOI: 10.1021/jacs.5b07492


403. Synthesis of Adjacent Quaternary Stereocenters by Catalytic Asymmetric Allylboration

Rauful Alam; Tobias Vollgraff; Lars Eriksson; Kálmán J. Szabó. J. Am. Chem. Soc. 2015, 137, 11262–11265. DOI: 10.1021/jacs.5b07498


404. Practical Pd(II)-Catalyzed C–H Alkylation with Epoxides: One-Step Syntheses of 3,4-Dihydroisocoumarins

Guolin Cheng; Tuan-Jie Li; Jin-Quan Yu. J. Am. Chem. Soc. 2015, 137, 10950–10953. DOI: 10.1021/jacs.5b07507


405. Oxalates as Activating Groups for Alcohols in Visible Light Photoredox Catalysis: Formation of Quaternary Centers by Redox-Neutral Fragment Coupling

Christopher C. Nawrat; Christopher R. Jamison; Yuriy Slutskyy; David W. C. MacMillan; Larry E. Overman. J. Am. Chem. Soc. 2015, 137, 11270–11273. DOI: 10.1021/jacs.5b07678


406. Palladium-Catalyzed Enantioselective 1,1-Fluoroarylation of Aminoalkenes

Ying He; Zhenyu Yang; Richard T. Thornbury; F. Dean Toste. J. Am. Chem. Soc. 2015, 137, 12207–12210. DOI: 10.1021/jacs.5b07795


407. Stereospecific Coupling of Boronic Esters with N-Heteroaromatic Compounds

Josep Llaveria; Daniele Leonori; Varinder K. Aggarwal. J. Am. Chem. Soc. 2015, 137, 10958–10961. DOI: 10.1021/jacs.5b07842


408. Synthesis of Hindered α-Amino Carbonyls: Copper-Catalyzed Radical Addition with Nitroso Compounds

David J. Fisher; G. Leslie Burnett; Rocío Velasco; Javier Read de Alaniz. J. Am. Chem. Soc. 2015, 137, 11614–11617. DOI: 10.1021/jacs.5b07860


409. Anti-Markovnikov Hydroheteroarylation of Unactivated Alkenes with Indoles, Pyrroles, Benzofurans, and Furans Catalyzed by a Nickel–N-Heterocyclic Carbene System

York Schramm; Makoto Takeuchi; Kazuhiko Semba; Yoshiaki Nakao; John F. Hartwig. J. Am. Chem. Soc. 2015, 137, 12215–12218. DOI: 10.1021/jacs.5b08039


410. Chiral Cationic CpxRu(II) Complexes for Enantioselective Yne-Enone Cyclizations

David Kossler; Nicolai Cramer. J. Am. Chem. Soc. 2015, 137, 12478–12481. DOI: 10.1021/jacs.5b08232


411. Fragment Couplings via CO2 Extrusion–Recombination: Expansion of a Classic Bond-Forming Strategy via Metallaphotoredox

Chi “Chip” Le; David W. C. MacMillan. J. Am. Chem. Soc. 2015, 137, 11938–11941. DOI: 10.1021/jacs.5b08304


412. Highly Selective Synthesis of Halomon, Plocamenone, and Isoplocamenone

Cyril Bucher; Richard M. Deans; Noah Z. Burns. J. Am. Chem. Soc. 2015, 137, 12784–12787. DOI: 10.1021/jacs.5b08398


413. Deoxygenative C–C Bond-Forming Processes via a Net Four-Electron Reductive Coupling

David P. Todd; Benjamin B. Thompson; Alex J. Nett; John Montgomery. J. Am. Chem. Soc. 2015, 137, 12788–12791. DOI: 10.1021/jacs.5b08448


414. Asymmetric Allylic C–H Oxidation for the Synthesis of Chromans

Pu-Sheng Wang; Peng Liu; Yu-Jia Zhai; Hua-Chen Lin; Zhi-Yong Han; Liu-Zhu Gong. J. Am. Chem. Soc. 2015, 137, 12732–12735. DOI: 10.1021/jacs.5b08477


415. Regio-, Diastereo-, and Enantioselective Nitroso-Diels–Alder Reaction of 1,3-Diene-1-carbamates Catalyzed by Chiral Phosphoric Acids

Jonathan Pous; Thibaut Courant; Guillaume Bernadat; Bogdan I. Iorga; Florent Blanchard; Géraldine Masson. J. Am. Chem. Soc. 2015, 137, 11950–11953. DOI: 10.1021/jacs.5b08515


416. Rapid, Regioconvergent, Solvent-Free Alkene Hydrosilylation with a Cobalt Catalyst

Chi Chen; Maxwell B. Hecht; Aydin Kavara; William W. Brennessel; Brandon Q. Mercado; Daniel J. Weix; Patrick L. Holland. J. Am. Chem. Soc. 2015, 137, 13244–13247. DOI: 10.1021/jacs.5b08611


417. Boron Tribromide-Assisted Chiral Phosphoric Acid Catalyst for a Highly Enantioselective Diels–Alder Reaction of 1,2-Dihydropyridines

Manabu Hatano; Yuta Goto; Atsuto Izumiseki; Matsujiro Akakura; Kazuaki Ishihara. J. Am. Chem. Soc. 2015, 137, 13472–13475. DOI: 10.1021/jacs.5b08693


418. Ligand-Enabled Meta-C–H Alkylation and Arylation Using a Modified Norbornene

Peng-Xiang Shen; Xiao-Chen Wang; Peng Wang; Ru-Yi Zhu; Jin-Quan Yu. J. Am. Chem. Soc. 2015, 137, 11574–11577. DOI: 10.1021/jacs.5b08914


419. Platinum-Catalyzed, Terminal-Selective C(sp3)–H Oxidation of Aliphatic Amines

Melissa Lee; Melanie S. Sanford. J. Am. Chem. Soc. 2015, 137, 12796–12799. DOI: 10.1021/jacs.5b09099


420. Phosphoric Acid-Catalyzed Asymmetric Classic Passerini Reaction

Jian Zhang; Shao-Xia Lin; Dao-Juan Cheng; Xin-Yuan Liu; Bin Tan. J. Am. Chem. Soc. 2015, 137, 14039–14042. DOI: 10.1021/jacs.5b09117


421. A Cu/Pd Cooperative Catalysis for Enantioselective Allylboration of Alkenes

Tao Jia; Peng Cao; Bing Wang; Yazhou Lou; Xuemei Yin; Min Wang; Jian Liao. J. Am. Chem. Soc. 2015, 137, 13760–13763. DOI: 10.1021/jacs.5b09146


422. Synergistic Catalysis of Ionic Brønsted Acid and Photosensitizer for a Redox Neutral Asymmetric α-Coupling of N-Arylaminomethanes with Aldimines

Daisuke Uraguchi; Natsuko Kinoshita; Tomohito Kizu; Takashi Ooi. J. Am. Chem. Soc. 2015, 137, 13768–13771. DOI: 10.1021/jacs.5b09329


423. Confined Acid-Catalyzed Asymmetric Carbonyl–Ene Cyclization

Luping Liu; Markus Leutzsch; Yiying Zheng; M. Wasim Alachraf; Walter Thiel; Benjamin List. J. Am. Chem. Soc. 2015, 137, 13268–13271. DOI: 10.1021/jacs.5b09484


424. Asymmetric Synthesis of β-Amino Amides by Catalytic Enantioconvergent 2-Aza-Cope Rearrangement

C. Guy Goodman; Jeffrey S. Johnson. J. Am. Chem. Soc. 2015, 137, 14574–14577. DOI: 10.1021/jacs.5b09593


425. Catalytic Olefin Hydroamidation Enabled by Proton-Coupled Electron Transfer

David C. Miller; Gilbert J. Choi; Hudson S. Orbe; Robert R. Knowles. J. Am. Chem. Soc. 2015, 137, 13492–13495. DOI: 10.1021/jacs.5b09671


426. Complete Switch of Selectivity in the C–H Alkenylation and Hydroarylation Catalyzed by Iridium: The Role of Directing Groups

Jiyu Kim; Sung-Woo Park; Mu-Hyun Baik; Sukbok Chang. J. Am. Chem. Soc. 2015, 137, 13448–13451. DOI: 10.1021/jacs.5b09824


427. Greater than the Sum of Its Parts: A Heterodinuclear Polymerization Catalyst

Jennifer A. Garden; Prabhjot K. Saini; Charlotte K. Williams. J. Am. Chem. Soc. 2015, 137, 15078–15081. DOI: 10.1021/jacs.5b09913


428. Stereoselective Catalysis Achieved through in Situ Desymmetrization of an Achiral Iron Catalyst Precursor

Cesar M. Manna; Aman Kaur; Lauren M. Yablon; Fredrik Haeffner; Bo Li; Jeffery A. Byers. J. Am. Chem. Soc. 2015, 137, 14232–14235. DOI: 10.1021/jacs.5b09966


429. Atroposelective Synthesis of Axially Chiral Biaryldiols via Organocatalytic Arylation of 2-Naphthols

Ye-Hui Chen; Dao-Juan Cheng; Jian Zhang; Yong Wang; Xin-Yuan Liu; Bin Tan. J. Am. Chem. Soc. 2015, 137, 15062–15065. DOI: 10.1021/jacs.5b10152


430. Catalytic Enantioselective Diarylation of Alkenes

Wei You; M. Kevin Brown. J. Am. Chem. Soc. 2015, 137, 14578–14581. DOI: 10.1021/jacs.5b10176


431. Dearomative Indole Cycloaddition Reactions of Aza-Oxyallyl Cationic Intermediates: Modular Access to Pyrroloindolines

Arjun Acharya; Devendar Anumandla; Christopher S. Jeffrey. J. Am. Chem. Soc. 2015, 137, 14858–14860. DOI: 10.1021/jacs.5b10184


432. Dearomative Indole (3 + 2) Reactions with Azaoxyallyl Cations – New Method for the Synthesis of Pyrroloindolines

Maria C. DiPoto; Russell P. Hughes; Jimmy Wu. J. Am. Chem. Soc. 2015, 137, 14861–14864. DOI: 10.1021/jacs.5b10221


433. Bifunctional Iminophosphorane Catalyzed Enantioselective Sulfa-Michael Addition to Unactivated α-Substituted Acrylate Esters

Alistair J. M. Farley; Christopher Sandford; Darren J. Dixon. J. Am. Chem. Soc. 2015, 137, 15992–15995. DOI: 10.1021/jacs.5b10226


434. Highly Selective Formation of n-Butanol from Ethanol through the Guerbet Process: A Tandem Catalytic Approach

Sumit Chakraborty; Paige E. Piszel; Cassandra E. Hayes; R. Tom Baker; William D. Jones. J. Am. Chem. Soc. 2015, 137, 14264–14267. DOI: 10.1021/jacs.5b10257


435. Silver-Catalyzed Long-Distance Aryl Migration from Carbon Center to Nitrogen Center

Taigang Zhou; Fei-Xian Luo; Ming-Yu Yang; Zhang-Jie Shi. J. Am. Chem. Soc. 2015, 137, 14586–14589. DOI: 10.1021/jacs.5b10267


436. Stereospecific Rhodium-Catalyzed Allylic Substitution with Alkenyl Cyanohydrin Pronucleophiles: Construction of Acyclic Quaternary Substituted α,β-Unsaturated Ketones

Ben W. H. Turnbull; Samuel Oliver; P. Andrew Evans. J. Am. Chem. Soc. 2015, 137, 15374–15377. DOI: 10.1021/jacs.5b10270


437. Remote Oxidation of Aliphatic C–H Bonds in Nitrogen-Containing Molecules

Jennifer M. Howell; Kaibo Feng; Joseph R. Clark; Louis J. Trzepkowski; M. Christina White. J. Am. Chem. Soc. 2015, 137, 14590–14593. DOI: 10.1021/jacs.5b10299


438. Asymmetric Catalysis with Ethylene. Synthesis of Functionalized Chiral Enolates

Souvagya Biswas; Jordan P. Page; Kendra R. Dewese; T. V. RajanBabu. J. Am. Chem. Soc. 2015, 137, 14268–14271. DOI: 10.1021/jacs.5b10364


439. Palladium-Catalyzed Intramolecular Aminotrifluoromethoxylation of Alkenes

Chaohuang Chen; Pinhong Chen; Guosheng Liu. J. Am. Chem. Soc. 2015, 137, 15648–15651. DOI: 10.1021/jacs.5b10971


440. Catalytic Asymmetric Iterative/Domino Aldehyde Cross-Aldol Reactions for the Rapid and Flexible Synthesis of 1,3-Polyols

Luqing Lin; Kumiko Yamamoto; Harunobu Mitsunuma; Yamato Kanzaki; Shigeki Matsunaga; Motomu Kanai. J. Am. Chem. Soc. 2015, 137, 15418–15421. DOI: 10.1021/jacs.5b11192


441. Asymmetric Copper-Catalyzed Carbozincation of Cyclopropenes en Route to the Formation of Diastereo- and Enantiomerically Enriched Polysubstituted Cyclopropanes

Daniel S. Müller; Ilan Marek. J. Am. Chem. Soc. 2015, 137, 15414–15417. DOI: 10.1021/jacs.5b11220


442. Enantioselective Dehydrogenative Heck Arylations of Trisubstituted Alkenes with Indoles to Construct Quaternary Stereocenters

Chun Zhang; Celine B. Santiago; Jennifer M. Crawford; Matthew S. Sigman. J. Am. Chem. Soc. 2015, 137, 15668–15671. DOI: 10.1021/jacs.5b11335


443. Design of a New Bimetallic Catalyst for Asymmetric Epoxidation and Sulfoxidation

Sukalyan Bhadra; Matsujiro Akakura; Hisashi Yamamoto. J. Am. Chem. Soc. 2015, 137, 15612–15615. DOI: 10.1021/jacs.5b11429


444. Boronic Acid-Catalyzed, Highly Enantioselective Aza-Michael Additions of Hydroxamic Acid to Quinone Imine Ketals

Takuya Hashimoto; Alberto Osuna Gálvez; Keiji Maruoka. J. Am. Chem. Soc. 2015, 137, 16016–16019. DOI: 10.1021/jacs.5b11518


445. Photoinduced Atom Transfer Radical Polymerization with ppm-Level Cu Catalyst by Visible Light in Aqueous Media

Xiangcheng Pan; Nikhil Malhotra; Antonina Simakova; Zongyu Wang; Dominik Konkolewicz; Krzysztof Matyjaszewski. J. Am. Chem. Soc. 2015, 137, 15430–15433. DOI: 10.1021/jacs.5b11599


446. Ambient-Temperature Newman–Kwart Rearrangement Mediated by Organic Photoredox Catalysis

Andrew J. Perkowski; Cole L. Cruz; David A. Nicewicz. J. Am. Chem. Soc. 2015, 137, 15684–15687. DOI: 10.1021/jacs.5b11800


447. Iridium-Catalyzed C–C Coupling of a Simple Propargyl Ether with Primary Alcohols: Enantioselective Homoaldol Addition via Redox-Triggered (Z)-Siloxyallylation

Tao Liang; Wandi Zhang; Michael J. Krische. J. Am. Chem. Soc. 2015, 137, 16024–16027. DOI: 10.1021/jacs.5b12131


Org. Lett.

448. Highly Enantioselective Copper-Catalyzed Propargylic Substitution of Propargylic Acetates with 1,3-Dicarbonyl Compounds

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449. Enantioselective Construction of Functionalized Thiopyrano-Indole Annulated Heterocycles via a Formal Thio [3 + 3]-Cyclization

Xiang Chen; Zheng-Hang Qi; Shao-Yun Zhang; Ling-Pei Kong; Yong Wang; Xing-Wang Wang. Org. Lett. 2015, 17, 42–45. DOI: 10.1021/ol503210q


450. Organocatalytic Enantioselective Addition of Thiols to Ketimines Derived from Isatins

Shuichi Nakamura; Shun Takahashi; Daisuke Nakane; Hideki Masuda. Org. Lett. 2015, 17, 106–109. DOI: 10.1021/ol503309s


451. Asymmetric Intermolecular Cobalt-Catalyzed Pauson–Khand Reaction Using a P-Stereogenic Bis-phosphane

Sílvia Orgué; Thierry León; Antoni Riera; Xavier Verdaguer. Org. Lett. 2015, 17, 250–253. DOI: 10.1021/ol503329g


452. Control of Five Contiguous Stereogenic Centers in an Organocatalytic Kinetic Resolution via Michael/Acetalization Sequence: Synthesis of Fully Substituted Tetrahydropyranols

Ramani Gurubrahamam; You-Song Cheng; Kwunmin Chen. Org. Lett. 2015, 17, 430–433. DOI: 10.1021/ol5033656


453. Highly Enantioselective [4 + 2] Cycloaddition of Allenoates and 2-Olefinic Benzofuran-3-ones

Feng Wang; Chao Luo; Ye-Ye Shen; Ze-Dong Wang; Xin Li; Jin-Pei Cheng. Org. Lett. 2015, 17, 338–341. DOI: 10.1021/ol503447z


454. Stereoselective Synthesis of Highly Substituted Cyclohexanes by a Rhodium-Carbene Initiated Domino Sequence

Brendan T. Parr; Huw M. L. Davies. Org. Lett. 2015, 17, 794–797. DOI: 10.1021/ol503508k


455. Chiral Phosphoric Acid Catalyzed Highly Enantioselective Friedel–Crafts Alkylation Reaction of C3-Substituted Indoles to β,γ-Unsaturated α-Ketimino Esters

Bo Bi; Qin-Xin Lou; Yu-Yang Ding; Sheng-Wei Chen; Sha-Sha Zhang; Wen-Hui Hu; Jun-Ling Zhao. Org. Lett. 2015, 17, 540–543. DOI: 10.1021/ol5035222


456. Copper-Catalyzed Enantioselective Intramolecular Aryl C–N Coupling: Synthesis of Enantioenriched 2-Oxo-1,2,3,4-tetrahydroquinoline-3-carboxamides via an Asymmetric Desymmetrization Strategy

Nian He; Yanping Huo; Jianguang Liu; Yusha Huang; Shasha Zhang; Qian Cai. Org. Lett. 2015, 17, 374–377. DOI: 10.1021/ol5035386


457. Pd-Catalyzed Asymmetric Intramolecular Aryl C–O Bond Formation with SDP(O) Ligand: Enantioselective Synthesis of (2,3-Dihydrobenzo[b][1,4]dioxin-2-yl)methanols

Jialing Shi; Ting Wang; Yusha Huang; Xinhao Zhang; Yun-Dong Wu; Qian Cai. Org. Lett. 2015, 17, 840–843. DOI: 10.1021/ol5036613


458. Directing Group Assisted Nucleophilic Substitution of Propargylic Alcohols via o-Quinone Methide Intermediates: Brønsted Acid Catalyzed, Highly Enantio- and Diastereoselective Synthesis of 7-Alkynyl-12a-acetamido-Substituted Benzoxanthenes

Satyajit Saha; Christoph Schneider. Org. Lett. 2015, 17, 648–651. DOI: 10.1021/ol503662g


459. Asymmetric Dearomatization of 1-Aminonaphthalene Derivatives by Gold-Catalyzed Intramolecular Double C–C Bond Formation

Junko Oka; Ryuichi Okamoto; Keiichi Noguchi; Ken Tanaka. Org. Lett. 2015, 17, 676–679. DOI: 10.1021/ol503698s


460. Double [3,3]-Sigmatropic Rearrangement in the Enzymatic Dioxygenation of Benzyl Azide: Preparation of Novel Synthetically Valuable Azido-diols

Natalia Thevenet; Victoria de la Sovera; María Agustina Vila; Nicolás Veiga; David Gonzalez; Gustavo Seoane; Ignacio Carrera. Org. Lett. 2015, 17, 684–687. DOI: 10.1021/ol503708v


461. Enantioselective Direct Mannich Reactions of Cyclic β-Ketoesters Catalyzed by Chiral Phosphine via a Novel Dual-Reagent Catalysis

Yan-Peng Lou; Chang-Wu Zheng; Ren-Ming Pan; Qiao-Wen Jin; Gang Zhao; Zhong Li. Org. Lett. 2015, 17, 688–691. DOI: 10.1021/ol503712m


Nature

462. High-value alcohols and higher-oxidation-state compounds by catalytic Z-selective cross-metathesis

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463. Non-stabilized nucleophiles in Cu-catalysed dynamic kinetic asymmetric allylic alkylation

[no graphical abstract]

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464. Silylation of C–H bonds in aromatic heterocycles by an Earth-abundant metal catalyst

[no graphical abstract]

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465. Ligand-enabled meta-C–H activation using a transient mediator

[no graphical abstract]

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[no graphical abstract]

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467. Multistep continuous-flow synthesis of (R)- and (S)-rolipram using heterogeneous catalysts

[no graphical abstract]

Tetsu Tsubogo; Hidekazu Oyamada; Shū Kobayashi. Nature. 2015, 520, 329–332. DOI: 10.1038/nature14343


468. Conversion of amides to esters by the nickel-catalysed activation of amide C–N bonds

[no graphical abstract]

Liana Hie; Noah F. Fine Nathel; Tejas K. Shah; Emma L. Baker; Xin Hong; Yun-Fang Yang; Peng Liu; K. N. Houk; Neil K. Garg. Nature. 2015, 524, 79–83. DOI: 10.1038/nature14615


469. Catalytic asymmetric umpolung reactions of imines

[no graphical abstract]

Yongwei Wu; Lin Hu; Zhe Li; Li Deng. Nature. 2015, 523, 445–450. DOI: 10.1038/nature14617


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471. Multimetallic catalysed cross-coupling of aryl bromides with aryl triflates

[no graphical abstract]

Laura K. G. Ackerman; Matthew M. Lovell; Daniel J. Weix. Nature. 2015, 524, 454–457. DOI: 10.1038/nature14676


472. Switching on elusive organometallic mechanisms with photoredox catalysis

[no graphical abstract]

Jack A. Terrett; James D. Cuthbertson; Valerie W. Shurtleff; David W. C. MacMillan. Nature. 2015, 524, 330–334. DOI: 10.1038/nature14875


473. Alcohols as alkylating agents in heteroarene C–H functionalization

[no graphical abstract]

Jian Jin; David W. C. MacMillan. Nature. 2015, 525, 87–90. DOI: 10.1038/nature14885


474. Rhodium-catalysed syn-carboamination of alkenes via a transient directing group

[no graphical abstract]

Tiffany Piou; Tomislav Rovis. Nature. 2015, 527, 86–90. DOI: 10.1038/nature15691


475. Organometallic palladium reagents for cysteine bioconjugation

[no graphical abstract]

Ekaterina V. Vinogradova; Chi Zhang; Alexander M. Spokoyny; Bradley L. Pentelute; Stephen L. Buchwald. Nature. 2015, 526, 687–691. DOI: 10.1038/nature15739


Nat. Chem.

476. Copper-catalysed selective hydroamination reactions of alkynes

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477. Catalytic, stereospecific syn-dichlorination of alkenes

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478. Atropselective syntheses of (−) and (+) rugulotrosin A utilizing point-to-axial chirality transfer

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479. Synthesis and characterization of hexaarylbenzenes with five or six different substituents enabled by programmed synthesis

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480. Terpene cyclization catalysed inside a self-assembled cavity

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481. Applying green chemistry to the photochemical route to artemisinin

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483. Enzymatic hydroxylation of an unactivated methylene C–H bond guided by molecular dynamics simulations

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484. A meta-selective C–H borylation directed by a secondary interaction between ligand and substrate

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485. Diverse sp3 C−H functionalization through alcohol β-sulfonyloxylation

Yan Xu; Guobing Yan; Zhi Ren; Guangbin Dong. Nat. Chem. 2015, 7, 829–834. DOI: 10.1038/nchem.2326


486. Formal SiH4 chemistry using stable and easy-to-handle surrogates

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487. Switchable selectivity in an NHC-catalysed dearomatizing annulation reaction

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488. A manganese catalyst for highly reactive yet chemoselective intramolecular C(sp3)–H amination

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489. A steric tethering approach enables palladium-catalysed C–H activation of primary amino alcohols

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Chem. Sci.

490. Enantioselective construction of C-chiral allylic sulfilimines via the iridium-catalyzed allylic amination with S,S-diphenylsulfilimine: asymmetric synthesis of primary allylic amines

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491. A catalytic asymmetric total synthesis of (−)-perophoramidine

B. M. Trost; M. Osipov; S. Krüger; Y. Zhang. Chem. Sci. 2014, 6, 349–353. DOI: 10.1039/C4SC01826E


492. Mechanistic insights into hydroacylation with non-chelating aldehydes

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493. Proxy-based accelerated discovery of Fischer–Tropsch catalysts

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494. Divergent regioselectivity in photoredox-catalyzed hydrofunctionalization reactions of unsaturated amides and thioamides

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495. Visible light C–H amidation of heteroarenes with benzoyl azides

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496. Structure–activity relationship studies of cyclopropenimines as enantioselective Brønsted base catalysts

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497. Enantioselective α-amination enabled by a BINAM-derived phase-transfer catalyst

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498. Mechanistic studies on covalent assemblies of metal-mediated hemi-aminal ethers

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499. Ligand design for Rh(III)-catalyzed C–H activation: an unsymmetrical cyclopentadienyl group enables a regioselective synthesis of dihydroisoquinolones

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500. Atom-economic generation of gold carbenes: gold-catalyzed formal [3+2] cycloaddition between ynamides and isoxazoles

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501. Stereoselective radical C–H alkylation with acceptor/acceptor-substituted diazo reagents via Co(II)-based metalloradical catalysis

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502. Stereoselective Lewis base catalyzed formal 1,3-dipolar cycloaddition of azomethine imines with mixed anhydrides

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503. The effect of host structure on the selectivity and mechanism of supramolecular catalysis of Prins cyclizations

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504. C–H arylation of triphenylene, naphthalene and related arenes using Pd/C

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505. Ligand functionalization as a deactivation pathway in a fac-Ir(ppy)3-mediated radical addition

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506. Development and investigation of a site selective palladium-catalyzed 1,4-difunctionalization of isoprene using pyridine–oxazoline ligands

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507. A dual catalytic strategy for carbon–phosphorus cross-coupling via gold and photoredox catalysis

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508. Asymmetric Lewis acid catalysis directed by octahedral rhodium centrochirality

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509. Cobalt co-catalysis for cross-electrophile coupling: diarylmethanes from benzyl mesylates and aryl halides

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510. Highly enantioselective access to diketopiperazines via cinchona alkaloid catalyzed Michael additions

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511. Selecting reactions and reactants using a switchable rotaxane organocatalyst with two different active sites

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512. Rh(III)-catalyzed C–H olefination of N-pentafluoroaryl benzamides using air as the sole oxidant

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513. Enantioselective installation of adjacent tertiary benzylic stereocentres using lithiation–borylation–protodeboronation methodology. Application to the synthesis of bifluranol and fluorohexestrol

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514. Enantioselective cis-β-lactam synthesis by intramolecular C–H functionalization from enoldiazoacetamides and derivative donor–acceptor cyclopropenes

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515. Enantioselective synthesis of D-α-amino amides from aliphatic aldehydes

Kenneth E. Schwieter; Jeffrey N. Johnston. Chem. Sci. 2015, 6, 2590–2595. DOI: 10.1039/C5SC00064E


516. Rhodium-catalyzed C–H functionalization-based approach to eight-membered lactams

Shangze Wu; Rong Zeng; Chunling Fu; Yihua Yu; Xue Zhang; Shengming Ma. Chem. Sci. 2015, 6, 2275–2285. DOI: 10.1039/C5SC00092K


517. Iron(II)-catalyzed asymmetric intramolecular olefin aminochlorination using chloride ion

Cheng-Liang Zhu; Jun-Shan Tian; Zhen-Yuan Gu; Guo-Wen Xing; Hao Xu. Chem. Sci. 2015, 6, 3044–3050. DOI: 10.1039/C5SC00221D


518. Gold(I)-catalyzed [2 + 2 + 2] cycloaddition of allenamides, alkenes and aldehydes: a straightforward approach to tetrahydropyrans

Hélio Faustino; Iván Varela; José L. Mascareñas; Fernando López. Chem. Sci. 2015, 6, 2903–2908. DOI: 10.1039/C5SC00295H


519. Enantioselective and diastereoselective azo-coupling/iminium-cyclizations: a unified strategy for the total syntheses of (−)-psychotriasine and (+)-pestalazine B

Qi Li; Tingting Xia; Licheng Yao; Haiteng Deng; Xuebin Liao. Chem. Sci. 2015, 6, 3599–3605. DOI: 10.1039/C5SC00338E


520. Using IR vibrations to quantitatively describe and predict site-selectivity in multivariate Rh-catalyzed C–H functionalization

Elizabeth N. Bess; David M. Guptill; Huw M. L. Davies; Matthew S. Sigman. Chem. Sci. 2015, 6, 3057–3062. DOI: 10.1039/C5SC00357A


521. Organocatalytic asymmetric chlorinative dearomatization of naphthols

Qin Yin; Shou-Guo Wang; Xiao-Wei Liang; De-Wei Gao; Jun Zheng; Shu-Li You. Chem. Sci. 2015, 6, 4179–4183. DOI: 10.1039/C5SC00494B


522. Rh-catalyzed decarbonylation of conjugated ynones via carbon–alkyne bond activation: reaction scope and mechanistic exploration via DFT calculations

Alpay Dermenci; Rachel E. Whittaker; Yang Gao; Faben A. Cruz; Zhi-Xiang Yu; Guangbin Dong. Chem. Sci. 2015, 6, 3201–3210. DOI: 10.1039/C5SC00584A


523. Enantioselective annulation of enals with 2-naphthols by triazolium salts derived from L-phenylalanine

Guo-Tai Li; Qing Gu; Shu-Li You. Chem. Sci. 2015, 6, 4273–4278. DOI: 10.1039/C5SC00731C


524. Enantioselective synthesis of bicyclo[3.n.1]alkanes by chiral phosphoric acid-catalyzed desymmetrizing Michael cyclizations

Alan R. Burns; Amaël G. E. Madec; Darryl W. Low; Iain D. Roy; Hon Wai Lam. Chem. Sci. 2015, 6, 3550–3555. DOI: 10.1039/C5SC00753D


525. Unified total synthesis of the natural products endiandric acid A, kingianic acid E, and kingianins A, D, and F

S. L. Drew; A. L. Lawrence; M. S. Sherburn. Chem. Sci. 2015, 6, 3886–3890. DOI: 10.1039/C5SC00794A


526. Sugar silanes: versatile reagents for stereocontrolled glycosylation via intramolecular aglycone delivery

Jordan T. Walk; Zachary A. Buchan; John Montgomery. Chem. Sci. 2015, 6, 3448–3453. DOI: 10.1039/C5SC00810G


527. Highly enantioselective sulfa-Michael addition reactions using N-heterocyclic carbene as a non-covalent organocatalyst

Jiean Chen; Sixuan Meng; Leming Wang; Hongmei Tang; Yong Huang. Chem. Sci. 2015, 6, 4184–4189. DOI: 10.1039/C5SC00878F


528. Copper-catalyzed diamination of unactivated alkenes with hydroxylamines

Kun Shen; Qiu Wang. Chem. Sci. 2015, 6, 4279–4283. DOI: 10.1039/C5SC00897B


529. Cobalt-catalysed asymmetric hydrovinylation of 1,3-dienes

Yam N. Timsina; Rakesh K. Sharma; T. V. RajanBabu. Chem. Sci. 2015, 6, 3994–4008. DOI: 10.1039/C5SC00929D


530. Palladium-catalyzed reductive coupling of phenols with anilines and amines: efficient conversion of phenolic lignin model monomers and analogues to cyclohexylamines

Zhengwang Chen; Huiying Zeng; Hang Gong; Haining Wang; Chao-Jun Li. Chem. Sci. 2015, 6, 4174–4178. DOI: 10.1039/C5SC00941C


531. Carbene catalyzed umpolung of α,β-enals: a reactivity study of diamino dienols vs. azolium enolates, and the characterization of advanced reaction intermediates

Veera Reddy Yatham; Jörg-M. Neudörfl; Nils E. Schlörer; Albrecht Berkessel. Chem. Sci. 2015, 6, 3706–3711. DOI: 10.1039/C5SC01027F


532. Diastereodivergent organocatalysis for the asymmetric synthesis of chiral annulated furans

Charlie Verrier; Paolo Melchiorre. Chem. Sci. 2015, 6, 4242–4246. DOI: 10.1039/C5SC01052G


533. Access to enantioenriched 2,3- and 2,5-dihydrofurans with a fully substituted C2 stereocenter by Pd-catalyzed asymmetric intermolecular Heck reaction

Gustavo M. Borrajo-Calleja; Vincent Bizet; Thomas Bürgi; Clément Mazet. Chem. Sci. 2015, 6, 4807–4811. DOI: 10.1039/C5SC01460C


534. Rh-catalyzed desymmetrization of α-quaternary centers by isomerization-hydroacylation

Jung-Woo Park; Kevin G. M. Kou; Daniel K. Kim; Vy M. Dong. Chem. Sci. 2015, 6, 4479–4483. DOI: 10.1039/C5SC01553G


535. Highly enantioselective construction of tertiary thioethers and alcohols via phosphine-catalyzed asymmetric γ-addition reactions of 5H-thiazol-4-ones and 5H-oxazol-4-ones: scope and mechanistic understandings

Tianli Wang; Zhaoyuan Yu; Ding Long Hoon; Kuo-Wei Huang; Yu Lan; Yixin Lu. Chem. Sci. 2015, 6, 4912–4922. DOI: 10.1039/C5SC01614B


536. Absolute structure determination of compounds with axial and planar chirality using the crystalline sponge method

Shota Yoshioka; Yasuhide Inokuma; Manabu Hoshino; Takashi Sato; Makoto Fujita. Chem. Sci. 2015, 6, 3765–3768. DOI: 10.1039/C5SC01681A


537. Configurationally stable, enantioenriched organometallic nucleophiles in stereospecific Pd-catalyzed cross-coupling reactions: an alternative approach to asymmetric synthesis

Chao-Yuan Wang; Joseph Derosa; Mark R. Biscoe. Chem. Sci. 2015, 6, 5105–5113. DOI: 10.1039/C5SC01710F


538. Ligand-enabled Ir-catalyzed intermolecular diastereoselective and enantioselective allylic alkylation of 3-substituted indoles

Xiao Zhang; Wen-Bo Liu; Hang-Fei Tu; Shu-Li You. Chem. Sci. 2015, 6, 4525–4529. DOI: 10.1039/C5SC01772F


539. Enantioselective gold-catalyzed intermolecular [2+2] versus [4+2]-cycloadditions of 3-styrylindoles with N-allenamides: observation of interesting substituent effects

Yidong Wang; Peichao Zhang; Yuan Liu; Fei Xia; Junliang Zhang. Chem. Sci. 2015, 6, 5564–5570. DOI: 10.1039/C5SC01827G


540. Enantioselective palladium(0)-catalyzed intramolecular cyclopropane functionalization: access to dihydroquinolones, dihydroisoquinolones and the BMS-791325 ring system

J. Pedroni; T. Saget; P. A. Donets; N. Cramer. Chem. Sci. 2015, 6, 5164–5171. DOI: 10.1039/C5SC01909E


541. Cooperative benzylic–oxyallylic stabilized cations: regioselective construction of α-quaternary centers in ketone-derived compounds

Nitin S. Dange; Jacob R. Stepherson; Caitlan E. Ayala; Frank R. Fronczek; Rendy Kartika. Chem. Sci. 2015, 6, 6312–6319. DOI: 10.1039/C5SC01914A


542. Cycloaddition of cyclobutenone and azomethine imine enabled by chiral isothiourea organic catalysts

Bao-Sheng Li; Yuhuang Wang; Zhichao Jin; Yonggui Robin Chi. Chem. Sci. 2015, 6, 6008–6012. DOI: 10.1039/C5SC01972A


543. Unstrained C–C bond activation and directed fluorination through photocatalytically-generated radical cations

Cody Ross Pitts; Michelle Sheanne Bloom; Desta Doro Bume; Qinze Arthur Zhang; Thomas Lectka. Chem. Sci. 2015, 6, 5225–5229. DOI: 10.1039/C5SC01973G


544. Catalytic asymmetric direct aldol reaction of α-alkyl azlactones and aliphatic aldehydes

Yang Zheng; Li Deng. Chem. Sci. 2015, 6, 6510–6514. DOI: 10.1039/C5SC02116B


545. Enantioselective reductive multicomponent coupling reactions between isatins and aldehydes

Matthew A. Horwitz; Naoya Tanaka; Takuya Yokosaka; Daisuke Uraguchi; Jeffrey S. Johnson; Takashi Ooi. Chem. Sci. 2015, 6, 6086–6090. DOI: 10.1039/C5SC02170G


546. Managing the retro-pathway in direct catalytic asymmetric aldol reactions of thioamides

Youmei Bao; Naoya Kumagai; Masakatsu Shibasaki. Chem. Sci. 2015, 6, 6124–6132. DOI: 10.1039/C5SC02218E


547. Application of a high-throughput enantiomeric excess optical assay involving a dynamic covalent assembly: parallel asymmetric allylation and ee sensing of homoallylic alcohols

H. H. Jo; X. Gao; L. You; E. V. Anslyn; M. J. Krische. Chem. Sci. 2015, 6, 6747–6753. DOI: 10.1039/C5SC02416A


548. Chiral ion-pair organocatalyst promotes highly enantioselective 3-exo iodo-cycloetherification of allyl alcohols

Zhigao Shen; Xixian Pan; Yisheng Lai; Jiadong Hu; Xiaolong Wan; Xiaoge Li; Hui Zhang; Weiqing Xie. Chem. Sci. 2015, 6, 6986–6990. DOI: 10.1039/C5SC02485D


549. Chiral phosphine-catalyzed tunable cycloaddition reactions of allenoates with benzofuranone-derived olefins for a highly regio-, diastereo- and enantioselective synthesis of spiro-benzofuranones

De Wang; Guo-Peng Wang; Yao-Liang Sun; Shou-Fei Zhu; Yin Wei; Qi-Lin Zhou; Min Shi. Chem. Sci. 2015, 6, 7319–7325. DOI: 10.1039/C5SC03135D


Science

550. A data-intensive approach to mechanistic elucidation applied to chiral anion catalysis

[no graphical abstract]

Anat Milo; Andrew J. Neel; F. Dean Toste; Matthew S. Sigman. Science. 2015, 347, 737–743. DOI: 10.1126/science.1261043


551. Rh-catalyzed C–C bond cleavage by transfer hydroformylation

[no graphical abstract]

Stephen K. Murphy; Jung-Woo Park; Faben A. Cruz; Vy M. Dong. Science. 2015, 347, 56–60. DOI: 10.1126/science.1261232


552. A rhodium catalyst for single-step styrene production from benzene and ethylene

[no graphical abstract]

Benjamin A. Vaughan; Michael S. Webster-Gardiner; Thomas R. Cundari; T. Brent Gunnoe. Science. 2015, 348, 421–424. DOI: 10.1126/science.aaa2260


553. Trapping a transition state in a computationally designed protein bottle

[no graphical abstract]

Aaron D. Pearson; Jeremy H. Mills; Yifan Song; Fariborz Nasertorabi; Gye Won Han; David Baker; Raymond C. Stevens; Peter G. Schultz. Science. 2015, 347, 863–867. DOI: 10.1126/science.aaa2424


554. A rational strategy for the realization of chain-growth supramolecular polymerization

[no graphical abstract]

Jiheong Kang; Daigo Miyajima; Tadashi Mori; Yoshihisa Inoue; Yoshimitsu Itoh; Takuzo Aida. Science. 2015, 347, 646–651. DOI: 10.1126/science.aaa4249


555. Synthesis of many different types of organic small molecules using one automated process

[no graphical abstract]

Junqi Li; Steven G. Ballmer; Eric P. Gillis; Seiko Fujii; Michael J. Schmidt; Andrea M. E. Palazzolo; Jonathan W. Lehmann; Greg F. Morehouse; Martin D. Burke. Science. 2015, 347, 1221–1226. DOI: 10.1126/science.aaa5414


556. Practical olefin hydroamination with nitroarenes

[no graphical abstract]

Jinghan Gui; Chung-Mao Pan; Ying Jin; Tian Qin; Julian C. Lo; Bryan J. Lee; Steven H. Spergel; Michael E. Mertzman; William J. Pitts; Thomas E. La Cruz; Michael A. Schmidt; Nitin Darvatkar; Swaminathan R. Natarajan; Phil S. Baran. Science. 2015, 348, 886–891. DOI: 10.1126/science.aab0245


557. Alkaline quinone flow battery

[no graphical abstract]

Kaixiang Lin; Qing Chen; Michael R. Gerhardt; Liuchuan Tong; Sang Bok Kim; Louise Eisenach; Alvaro W. Valle; David Hardee; Roy G. Gordon; Michael J. Aziz; Michael P. Marshak. Science. 2015, 349, 1529–1532. DOI: 10.1126/science.aab3033


558. Metal-free catalytic C-H bond activation and borylation of heteroarenes

[no graphical abstract]

Marc-André Légaré; Marc-André Courtemanche; Étienne Rochette; Frédéric-Georges Fontaine. Science. 2015, 349, 513–516. DOI: 10.1126/science.aab3591


559. Catalytic asymmetric hydroamination of unactivated internal olefins to aliphatic amines

[no graphical abstract]

Yang Yang; Shi-Liang Shi; Dawen Niu; Peng Liu; Stephen L. Buchwald. Science. 2015, 349, 62–66. DOI: 10.1126/science.aab3753


560. Sustainable Fe–ppm Pd nanoparticle catalysis of Suzuki-Miyaura cross-couplings in water

[no graphical abstract]

Sachin Handa; Ye Wang; Fabrice Gallou; Bruce H. Lipshutz. Science. 2015, 349, 1087–1091. DOI: 10.1126/science.aac6936


561. Iron-catalyzed intermolecular [2+2] cycloadditions of unactivated alkenes

[no graphical abstract]

Jordan M. Hoyt; Valerie A. Schmidt; Aaron M. Tondreau; Paul J. Chirik. Science. 2015, 349, 960–963. DOI: 10.1126/science.aac7440


562. O–H hydrogen bonding promotes H-atom transfer from α C–H bonds for C-alkylation of alcohols

[no graphical abstract]

Jenna L. Jeffrey; Jack A. Terrett; David W. C. MacMillan. Science. 2015, 349, 1532–1536. DOI: 10.1126/science.aac8555


563. Conversion of alcohols to enantiopure amines through dual-enzyme hydrogen-borrowing cascades

[no graphical abstract]

Francesco G. Mutti; Tanja Knaus; Nigel S. Scrutton; Michael Breuer; Nicholas J. Turner. Science. 2015, 349, 1525–1529. DOI: 10.1126/science.aac9283


564. Site-selective arene C-H amination via photoredox catalysis

[no graphical abstract]

Nathan A. Romero; Kaila A. Margrey; Nicholas E. Tay; David A. Nicewicz. Science. 2015, 349, 1326–1330. DOI: 10.1126/science.aac9895


565. A supramolecular microenvironment strategy for transition metal catalysis

[no graphical abstract]

David M. Kaphan; Mark D. Levin; Robert G. Bergman; Kenneth N. Raymond; F. Dean Toste. Science. 2015, 350, 1235–1238. DOI: 10.1126/science.aad3087